Registration Dossier
Registration Dossier
Data platform availability banner - registered substances factsheets
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 427-700-2 | CAS number: 15606-95-8 TRIETHYLARSENAT; TRIETHYLARSENATE; TRIETHYLARSENATE (TEASAT)
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
Emergency measure - Inhalation: Entfernen aus der gashaltigen Atmosphäre. Gefahr für den
Helfer einschätzen.
Frischluft, Atemwege freihalten, Auxiloson-Spray (3-4 Hübe)
einatmen lassen, bequem lagern, Ruhe, Wärme, Transport in
stabiler Seitenlage.
Sofort Arzt hinzuziehen. Bei Atemstillstand sofort
künstliche Beatmung. Bei aussetzendem Puls Herzmassage
durchführen.
In allen Fällen ist eine ärztliche Kontrolle über 48 Stunden
notwendig, da Vergiftungserscheinungen erst nach 2 Tagen
auftreten können.
"ENGLISH"
Remove from the gas-containing atmosphere. Estimate the risk
for helpers.
Fresh air, keep the respiratory tract clear, get the
affected person to inhale auxiloson spray (3-4 jets), place
in a comfortable position, rest, warmth, transport in a
stable lateral position.
Seek medical advice immediately. Immediate artificial
respiration in the case of cessation of breathing.
Perform heart massage if the pulse is irregular.
Medical supervision over 48 hours is required in all cases
since signs of intoxication may not occur until 2 days
later.
Emergency measure - Eyes: Sofort mit viel Wasser bei geöffnetem
Lidspalt ausspülen. Arzt konsultieren.
"ENGLISH"
Keeping the eyelids open, rinse with large quantities of
water immediately. Seek medical advice.
Emergency measure - Skin: Sofort mit viel Wasser abwaschen.
Verunreinigte Kleidung sofort entfernen. Arzt konsultieren.
"ENGLISH"
Wash off immediately with large quantities of water. Remove
contaminated clothing immediately. Seek medical advice.
Emergency measure - Ingestion: Solange der Betroffene bei Bewußtsein ist, ca. 500 ml Wasser
trinken lassen und Erbrechen herbeiführen. Achtung,
Erbrochenes nicht in die Lunge gelangen lassen.
Danach 2 Löffel Aktivkohle in etwa 500 ml Wasser trinken.
Sofort Arzt hinzuziehen.
"ENGLISH"
Provided that the affected person is conscious, get him or
her to drink approx. 500 ml of water and induce vomiting.
Attention, do not allow vomit to enter the lung. Then
get the person to drink 2 spoonsful of activated carbon in
approx. 500 ml of water. Seek medical advice immediately.
Fire-fighting measures
Recommended extinguishing agent: Trockenpulver
"ENGLISH"
Dry powder
Product arising from burning: Arsenoxid, Arsenwasserstoff, Kohlendioxid, Wasser
"ENGLISH"
Arsenic oxide, arsenic trihydride, carbon dioxide, water
Product determined by test: N
Protective equipment: Umlufunabhängiges Atemschutzgerät
Schutzausrüstung aus feuerfestem Material
dichtschliessender Chemieschutzanzug
"ENGLISH"
Self-contained respirator
Protection equipment from fireresistent material
tightly closable chemical protective suit
Accidental release measures
Emergency measures in case of spillage: Nach Verschütten und Auslaufen kleinerer Mengen: Flüssigkeit
mit flüssigkeitsbindendem Material (z.B. Sand, Chemisorb)
aufnehmen und in geschlossenem Behälter der Entsorgung
zuführen. Der Behälter ist nach TRGS 201 "Kennzeichnung von
Abfällen beim Umgang" mit T"giftig" zu kennzeichnen.
Flüssigkeit nicht ins Erdreich oder Gewässer laufen lassen.
Die persönliche Schutzausrüstung ist anzulegen bestehend aus
Augenschutz (z.B. Schutzbrille), Fußschutz (geschlossenes
Schuhwerk), Schutzkleidung (z.B. Laborkittel), Atemschutz
(falls offene Handhabung außerhalb des Abzugs notwendig:
mindestens Halbmaske mit Kombinationsfilter A2P3).
Beim Auslaufen größerer Mengen: Sofort Werkfeuerwehr und
Umweltschutzabteilung benachrichtigen.
"ENGLISH"
After spillage and leakage of fairly small quantities: take
up the liquid with a liquid-binding material (e.g. sand,
chemisorb) and use a closed container for the purpose of
disposal. Label the container with T "toxic". Do not permit
release of the liquid into the soil or aquatic environments.
Use personal protective equipment consisting of eye
protection (e.g. goggles), foot protection (closed shoes),
protective clothing (e.g. white laboratory coat),
respiratory protection (in case open handling outside the
fume cupboard is necessary): at least a half mask with an
A2P3 combination filter).
In the case of leakage of larger quantities: inform the
works fire service and the environmental protection
department immediately.
Handling and storage
Handling: Bei Zutritt von Luft und/oder Wasser wird das Produkt
hydrolysiert, wobei sich giftige Arsensäure und Ethanol
bildet. Alle Arsenverbindungen sind als krebserzeugend,
Kat.1 eingestuft.
Es wird empfohlen, das Produkt im Originalbehälter (i.a.
Edelstahlcontainer) unter Schutzgas (Argon bzw. Stickstoff)
zu halten. Das Produkt sollte ausschließlich unter
Inertgasbedingungen in geschlossenen Systemen gehandhabt
werden. Bei Abfüll-, Umfüll- und Dosierarbeiten sowie
Probenahmen sind geschlossene Vorrichtungen oder
Vorrichtungen mit lokaler Absaugung, ohne Rückführung der
abgesaugten Luft in die Arbeitsbereichsatmosphäre, zu
verwenden. Es werden krebserzeugende Eigenschaften vermutet.
Die persönliche Schutzausrüstung besteht aus: Atem-,
Augen-, Hand- und Fußschutz sowie Schutzkleidung
(s. "Vorsichtsmaßmahmen bei unbeabsichtigtem Verbreiten").
Siehe auch: VBG 113 Umgang mit krebserzeugenden
Gefahrstoffen. Alle Arbeitsverfahren sind so zu gestalten,
daß das Einatmen des Stoffes sowie Haut- und Augenkontakt
ausgeschlossen wird. Arbeitskleidung bzw. Schutzkleidung
getrennt von Straßenkleidung aufbewahren.
"ENGLISH"
The product is hydrolysed on contact with air and/or water.
Toxic arsenic acid and ethanol are formed in the process.
All arsenic compounds are classified as carcinogenic, cat.
1.
It is recommended that the product be kept in the original
container (i.a. high-quality steel containers) in
protective gas (argon or nitrogen). The product should be
handled under inert gas conditions in closed systems only.
Closed equipment or equipment with local exhaust
ventilation, without return of the exhaust air to the
workplace atmosphere, must be used during filling,
transfer, metering and sampling. Carcinogenic properties
are assumed. The personal protective equipment consists of:
respiratory, eye, hand and foot protection as well as
protective clothing (see "precautionary measures in the
case of accidental spillage"). All of the work processes
must be designed in such a way that inhalation of the
substance as well as skin and eye contact are excluded.
Keep work clothing or protective clothing separate from
outdoor clothes.
Storage: Es wird empfohlen, das Produkt im dicht geschlossenen,
vorschriftsmäßig gekennzeichnetem Originalbehälter (i.a.
Edelstahl-, Glascontainer) unter Schutzgas (Argon bzw.
Stickstoff) zu lagern. Produkt trocken, kühl und dunkel
lagern. Behälter- falls notwendig- nur unter lokaler
Absaugung (ohne Rückführung der abgesaugten Luft)
kurzfristig öffnen, danach sorgfältig verschließen und
aufrecht lagern, um jegliches Auslaufen zu
verhindern. Flüssigkeit vor Verdunstung bewahren.
Die TRGS 514 ist zu beachten.
"ENGLISH"
It is recommended that the product be stored in tightly
closed original containers (i.a. high-quality
containers, glass containers), which are labelled
according to the regulations, in protective gas (argon
or nitrogen). Store the product in a dry, cool and dark
place. If necessary, open the containers for a short time
using local exhaust ventilation only (without return of the
exhaust air), close carefully again and store upright in
order to avoid any leakage. Protect liquid against
evaporation.
Packaging of the substance and or preparation: Verpackungsmaterial z.Zt. Edelstahlbehälter:
Gewicht ca. 5,8 kg
Volumen ca. 1,7 l
"ENGLISH"
Packaging material currently high-quality steel containers:
Weight approx. 5.8 kg
Volume approx. 1.7 l
Transport information
Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Transport code: UN-Nr.: 1556
Transport: 1. Innerbetriebliche Beförderung von Probemengen bis zu 30
ml: Transport in dicht verschlossener Glasflasche, die in
einer widerstandsfähigen Außenverpackung untergebracht ist.
Beide Behälter müssen mit Etikett nach TRGS 200
gekennzeichnet sein.
2. Innerbetriebliche Beförderung für den Versand in
zugelassenen Behältern (i.A. Edelstahlflaschen mit
gesicherten Ventilen) entsprechend den
Transportvorschriften. Falls der Transport in Glasgebinden
notwendig ist, so ist dieser in geeigneten Umverpackungen,
ggf. umgeben von aufsaugenden Materialien, durchzuführen.
Behälter vor dem Transport dicht verschließen.
Vorschriftsmäßige Kennzeichnung der Behälter.
In beiden Fällen sind die Behälter beim Transport mit
Fahrzeugen gegen Herabfallen zu sichern.
Weitere Transport-Codes:
GGVE/GGVS/RID/ADR: 6.1 Ziffer 51 b PG:II
GGVSee/IMDG: 6.1 UN-Nr.: 1556 PG:II
ICAO/IATA: 6.1 UN-Nr.: 1556 PG:II
"ENGLISH"
1. In-company transportation of sample quantities up to 30
ml: transportation in a tightly closed glass bottle which is
placed in resistant outer packaging. Both of the containers
must be labelled.
2. In-company transportation for dispatch in approved
containers (i.a. high-quality steel bottles with a protected
valve) in accordance with the transport regulations. If
transportation in glass vessels is necessary, suitable outer
packaging, possibly surrounded by absorbent material, must
be used. Tightly close containers prior to transportation.
Label the containers in accordance with the regulations.
In both cases, the containers must be secured against
falling during transportation by vehicles.
Further transport codes:
GGVE/GGVS/RID/ADR: 6.1 section 51 b PG:II
GGVSee/IMDG: 6.1 UN no.: 1556 PG:II
ICAO/IATA: 6.1 UN no.: 1556 PG:II
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Stability and reactivity
Danger other than fire: Arsenwasserstoff-Gasentwicklung bei Reaktion mit Zn, Al und
Basen/Säuren.
"ENGLISH"
The formation of arsenic trihydride gas on reaction with Zn,
Al and bases/acids.
Chemical reaction with water: Hydrolysiert mit Wasser unter Bildung von giftiger
Arsensäure und Ethanol.
"ENGLISH"
Hydrolyses with water forming toxic arsenic acid and
ethanol.
Dust explosion determined by test: N
Disposal considerations
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.