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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Surface tension

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Reference
Endpoint:
surface tension
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP Guideline Study
Qualifier:
according to guideline
Guideline:
EU Method A.5 (Surface Tension)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
plate method
Surface tension:
72.2 mN/m
Temp.:
20 °C
Conc.:
1 g/L

Result:

 Test  Time [min]  Surface tension at 20 °C [mN/m]
 1st value  10  72.3
 2nd value  37  72.2
 3nd value  65  72.1
 4nd value  103  72.2
 Mean value  ---  72.2

For verification of the measured values the surface tension of demineralized water was also measured. With a correspondence of the measured value σ (20 °C) = 72.5 mN/m, to the theoretical value σ (20 °C) = 72.75 mN/m, cited in literature, the determination of the surface tension of PDI is considered as valid.

Conclusions:
The surface tension is 72.2 mN/m (diluted to 1 g/L in water at 20°C)
Executive summary:

According to EU Method A. 5 the surface tension is 72.2 mN/m. A commercially available tensiometer based on the plate method has been used to measure the force which is required to withdraw a horizontally suspended plate from the surface of the test item. The surface tension was determined in a solution of 1.0003 g test item in 1 L demineralized water (approx. 1 g/L) at 20 °C. After 24 h stirring a clear measuring solution was obtained and no particles were visible. For verification of the measured values the surface tension of demineralized water was also measured. With a correspondence of the measured value σ (20 °C) = 72.5 mN/m, to the theoretical value σ (20 °C) = 72.75 mN/m, cited in literature, the determination of the surface tension of PDI item is considered as valid.

Description of key information

The surface tension is 72.2 mN/m (diluted to 1 g/L in water at 20°C) 

Key value for chemical safety assessment

Surface tension:
72.2
in mN/m at 20°C and concentration in mg/L:
1 000.3

Additional information

For verification of the measured values the surface tension of demineralized water was also measured. With a correspondence of the measured value σ (20 °C) = 72.5 mN/m, to the theoretical value σ (20 °C) = 72.75 mN/m, cited in literature, the determination of the surface tension of the substance is considered as valid.

It should be made clear that the substance hydrolyses rapidly and thus during measurement most of the substance had been disappeared.