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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
27 March to 22 April 2013
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.7950 (Vapor Pressure)
Principles of method if other than guideline:
Not applicable
GLP compliance:
yes (incl. QA statement)
Type of method:
gas saturation method
Key result
Temp.:
20 °C
Vapour pressure:
0.027 Pa

Headspace vapour concentrations of test item as found after an equilibration time of 5 h, 24 h and 28 h are tabulated below. The value obtained after an equilibration time of 2 h was not used for the calculation of the vapour pressure, as it can be deduced from the results that headspace saturation was not yet reached.

 

Table 4.6/1: Headspace concentration of test item

Equilibration time (h)

Headspace concentration (g/m3)

5

0.0021

24

0.0020

28

0.0024

Average

0.0022

 

Conclusions:
Low volatility (based on volatility bands criteria for occupational exposure (Chesar / ECETOC TRA), << 500 Pa).
Executive summary:

The vapour pressure of the test material was determined according to the OECD guideline No. 104 (headspace method, similar to the gas saturation method), and under GLP.

 

After equilibration, the concentration in the vapour phase was measured in triplicate.

The vapour pressure at 20°C was calculated from the average headspace concentration using the vapour pressure equation.

The Vapour pressure of the test item is 0.027 Pa at 20°C.

Description of key information

Low volatility.

Key value for chemical safety assessment

Vapour pressure:
0.027 Pa
at the temperature of:
20 °C

Additional information

A fully reliable experimental study, conducted according to a recognized OECD method and under GLP, is available.

It is considered as a key study; the result is retained as key data for CSA.