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EC number: 401-800-6 | CAS number: 101513-70-6 3,5-DICHLORO-2,4-DIFLUOROBENZOYLFLUORIDE
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation: Get medical attention immediately. Move affected person to fresh air.
If it is suspected that fumes are still present, the rescuer should wear
an appropriate mask or self-contained breathing apparatus. Keep
person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
After inhalation take calcium tablets as for skin contact. Treat with a
corticoid metered aerosol depending on the amount inhaled. If
appropriate symptoms occur or inhalation of large quantities is
suspected, administer cortisone intravenously in addition
Ingestion: Get medical attention immediately. Wash out mouth with water.
Move exposed person to fresh air. Keep person warm and at rest. If
material has been swallowed and the exposed person is conscious,
give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs.
Chemical burns must be treated promptly by a physician. Never give
anything by mouth to an unconscious person. If unconscious, place
in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact: Get medical attention immediately. Flush contaminated skin with
plenty of water. Remove contaminated clothing and shoes. Continue
to rinse for at least 10 minutes. Chemical burns must be treated
promptly by a physician. In the event of any complaints or symptoms,
avoid further exposure. Wash clothing before reuse. Clean shoes
thoroughly before reuse.
Apply calcium gluconate gel to the affected area, rub in until locally
free of pain and then continue for further 15 minutes. If possible
apply a dressing soaked in 20% calcium gluconate solution. If burns
cover more than area of the hand ( = approx. 150 cm²)
6 effervescent calcium pills (400 mg calcium per pill) must be
dissolved in water and taken orally. This dose should be repeated
every 2 hours until the patient is in hospital. If burns cover large
areas patient should be completely bathed in at least 1% calcium
gluconate solution. If burns cover large areas patient should be
completely bathed in at least 1% calcium gluconate solution.
Eye contact: Get medical attention immediately. Immediately flush eyes with
plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at
least 10 minutes. Chemical burns must be treated promptly by a physician.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Use dry chemical or CO2.
Unsuitable extinguishing media: Do not use water or foam.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: Contact with water liberates toxic gas. In a fire or if heated, a
pressure increase will occur and the container may burst.
Hazardous combustion products: Decomposition products may include the following materials:
carbon oxides
halogenated compounds
Advice for firefighters
Special precautions for firefighters: Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. This material is harmful to
aquatic organisms. Fire water contaminated with this material must
be contained and prevented from being discharged to any waterway, sewer or drain.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and selfcontained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Accidental release measures
Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep unnecessary
and unprotected personnel from entering. Do not touch or walk
through spilt material. Keep away from water. Avoid breathing
vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment.
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air). Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Methods and materials for containment and cleaning up:
Small spill: Stop leak if without risk. Move containers from spill area. Avoid
allowing the spilled material to get wet or using water to clean up
spillages or residues, unless the quantity remaining is very small.
Absorb with an inert material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Prevent
entry into sewers, water courses, basements or confined areas.
Avoid allowing the spilled material to get wet or using water to clean
up spillages or residues, unless the quantity remaining is very small.
Contain and collect spillage with non-combustible, absorbent
material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilt product.
Handling and storage
Manufacture and use of this chemical intermediate takes place under strictly controlled conditions, as described in Art. 17/18 REACH. The substance is rigorously contained during manufacturing and use and appropriate risk management measures including PPE (i.g. during charging or sampling) are applied. Occupational exposure is reduced to a minimum and well controlled by measurements. A management system covering all general aspectsof a chemical production is in place, especially cleaning and maintenance of plants and equipment. An authorisation scheme based on instructions covering the whole process ensures that only trained and authorised staff handles the substance.
Put on appropriate personal protective equipment.
Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Persons with a
history of skin sensitization problems should not be employed in any
process in which this product is used. Do not get in eyes or on skin or
clothing. Do not breathe vapour or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use.
Keep away from water. Empty containers retain product residue and
can be hazardous.
The product is registered with strictly controlled conditions as defined in Article 17(3) or 18(4) of the regulation
(EC) no. 1907/2006 (REACH regulation) and must therefore be handled as
such. Refer to the industry guidance prepared by Concawe/Cefic/
EFCG for advice on the confirmation of strictly controlled conditions.
Conditions for safe storage, including any incompatibilities
Do not store below the following temperature: -10°C (14°F). Store in
accordance with local regulations. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area,
away from incompatible materials and food and
drink. Keep away from water. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage. Do not
store in unlabelled containers. Use appropriate containment to avoid
environmental contamination.
Seveso II Directive - Reporting thresholds (in tonnes)
Danger criteria
Category
H2: Acute toxicity 2 any route of entry or Acute toxicity 3 Inhalation/Dermal route of entry
Notification and MAPP threshold: 50
Safety report threshold: 200
C2: Toxic
Notification and MAPP threshold: 50
Safety report threshold: 200
C10ii: Liberates toxic gas in contact with water
Notification and MAPP threshold: 50
Safety report threshold: 200
Remarks : Ensure effective ventilation. Vent waste air only via suitable
separators or scrubbers. Take precautionary measures against
electrostatic discharges.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Exposure limit values : Not available.
Recommended monitoring procedures:If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be required.
Exposure controls
Risk management measures
Occupational exposure controls
Technical measures:
The substance shall be rigorously contained by technical means
during its whole lifecycle including manufacture, purification,
cleaning and maintenance of equipment, sampling, analysis,
loading and unloading of equipment or vessels, waste disposal or
purification and storage. Procedural and control technologies shall
be used that minimise emission and any resulting exposure. In
cases of accident and where waste is generated, procedural and/
or control technologies shall be used to minimise emissions and
the resulting exposure during purification or cleaning and
maintenance procedures.
Organisational measures:
Only properly trained and authorised personnel should handle the
substance. In the case of cleaning and maintenance works,
special procedures such as purging and washing shall be applied
before the system is opened and entered.
Personal protection measures
Respiratory protection:
If exposure cannot be ruled out, e.g. during product transfer,
sampling or maintenance, a well-fitting respiratory mask
conforming to standards or well-fitting respiratory device conforming to standards must be worn. Respirator selection must
be based on known or anticipated exposure levels, the hazards of
the product and the safe working limits of the selected respirator.
Recommended: Full mask with type ABEK filter. Wear breathing apparatus with separate air supply (compressed air
respirator, tube apparatus) at higher concentrations.
Hand protection:
Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if product contact cannot be excluded. After
contamination with product change the gloves immediately and
dispose of them according to relevant national and local
regulations
Recommended: (< 1 hour) Butyl rubber - IIR , Fluorinated rubber -
FKM or polyvinyl chloride (PVC)
Eye protection:
Safety eyewear complying with an approved standard should be
used to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: safety glasses with side-shields
Skin protection:
Wear protective clothing. Personal protective equipment for the
body should be selected based on the task being performed and
the risks involved and should be approved by a specialist before
handling this product.
Recommended: Recommended: Wear protective clothing.
Hygiene measures : Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the lavatory
and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash
stations and safety showers are close to the workstation location.
Environmental exposure controls
Technical measures : Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Stability and reactivity
Reactivity: No specific test data related to reactivity available for this product or
its ingredients.
Chemical stability: The product is stable.
Possibility of hazardous reactions:
Hazardous reactions or instability may occur under certain conditions
of storage or use.
Conditions may include the following:
contact with water
Reactions may include the following: liberation of toxic gas
Conditions to avoid : Incompatibility with various substances: water, alcohols, amines,
mercaptanes, iron, aluminium and zinc. Compound decomposes in
the presence of water, therefore exclusion of moisture.
Incompatible materials : Reactive or incompatible with the following materials: Water
Hazardous decomposition products: Contact with water liberates toxic gas.
Disposal considerations
Waste treatment methods
Product
Methods of disposal:
Examine possibilities for re-utilisation. Product residues and
uncleaned empty containers should be packaged, sealed, labelled,
and disposed of or recycled according to relevant national and local
regulations. Where large quantities are concerned, consult the
supplier. When uncleaned empty containers are passed on, the
recipient must be warned of any possible hazard that may be caused
by residues. For disposal within the EC, the appropriate code
according to the European Waste List (EWL) should be used. It is
among the tasks of the polluter to assign the waste to waste codes
specific to industrial sectors and processes according to the
European Waste List (EWL).
Hazardous waste: The classification of the product may meet the criteria for a
hazardous waste.
Packaging
Methods of disposal:
The generation of waste should be avoided or minimised wherever
possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.
Special precautions:
This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.