Propanoic acid, 2-fluoro-, methyl ester, (2R)-

Guidance on Safe Use

First-aid measures

General advice :

   In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). First aider needs to protect himself. Move out of dangerous area. Never give anything by mouth to an unconscious person. Take off contaminated clothing and shoes immediately.

Inhalation :

   If breathed in, move person into fresh air. Call a physician immediately. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Skin contact :

   In case of contact, immediately flush skin with soap and plenty of water. Do NOT use solvents or thinners. If skin irritation

persists, call a physician.

Eye contact :

   Protect unharmed eye. If easy to do, remove contact lens, if worn. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion :

   If swallowed, seek medical advice immediately and show this container or label. If swallowed, DO NOT induce vomiting. If a person vomits when lying on his back, place him in the recovery position.

Fire-fighting measures

Suitable extinguishing media :

   Water spray jet, Carbon dioxide (CO2), Dry chemical, Foam

Unsuitable extinguishing media:

   High volume water jet

Specific hazards :

   Do not use a solid water stream as it may scatter and spread fire. Hazardous decomposition products may be formed under

fire conditions (see section 10). Exposure to decomposition products may be a hazard to health.

Special protective equipment for fire-fighters:

   In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

Further information :

   Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Pay attention to flashback.

Accidental release measures

Personal precautions :

   Refer to protective measures listed in sections 7 and 8. Use personal protective equipment. Remove all sources of ignition. Avoid contact with skin and eyes. Ensure adequate ventilation, especially in confined areas. Immediately evacuate personnel to safe areas. Avoid inhalation of vapour or mist. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.

Environmental precautions :

   Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up :

   Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations. Clean contaminated surface thoroughly.

Handling and storage

Handling

Advice on safe handling :

   For personal protection see section 8. Do not breathe vapours or spray mist. Avoid contact with skin and eyes. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Take precautionary measures against static discharges.

Advice on protection against fire and explosion :

   Normal measures for preventive fire protection. Keep away from heat and sources of ignition. Do not smoke. No sparking tools should be used. Electrical equipment should be protected to the appropriate standard.

   

Dust explosion class :

   not applicable

Storage

Requirements for storage areas and containers :

   Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat. Keep away from direct sunlight.

Advice on common storage :

   Incompatible with oxidizing agents. Keep away from food, drink and animal feedingstuffs.

   

Other data :

   No decomposition if stored and applied as directed.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3272

Shipping information

Proper shipping name and description:

ESTERS, N.O.S.
(Methyl-2-fluoropropionate)

Chemical name:

ESTERS, N.O.S.
(Methyl-2-fluoropropionate)

Labels:

3

Special provisions / remarks

Special provisions:

Limited quantity : LQ7
Tunnel restriction code : (D/E)
Environmentally hazardous : no

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3272

Shipping

Labels:

3

Special provisions / remarks

Remarks:

Limited quantity : LQ7
Tunnel restriction code : (D/E)
Environmentally hazardous : no

Marine transport (UN RTDG/IMDG)

UN number:

3272

Shipping information

Proper shipping name and description:

ESTERS, N.O.S.
(Methyl-2-fluoropropionate)

Chemical name:

ESTERS, N.O.S.
(Methyl-2-fluoropropionate)

Labels:

3

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3272

Shipping information

Proper shipping name and description:

Esters, n.o.s.
(Methyl-2-fluoropropionate)

Chemical name:

Esters, n.o.s.
(Methyl-2-fluoropropionate)

Labels:

3

Special provisions / remarks

Remarks:

Packing instruction (cargoaircraft): 310
Environmentally hazardous : no Packing instruction (passengeraircraft): 309
Packing instruction (LQ) : Y309

SpecialProvisions

Exposure controls / personal protection

Components with workplace control parameters

   Contains no substances with occupational exposure limit values.

   Other information on limit values: see chapter 16

Engineering measures

   Provide sufficient air exchange and/or exhaust in work rooms.

Personal protective equipment

   Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator with filter type ABEK

   

Hand protection

   Material : Rubber gloves

   Remarks : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer.

   Eye protection : Tightly fitting safety goggles

   Skin and body protection : Flame retardant antistatic protective clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.

   Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. General industrial hygiene practice. Avoid breathing vapors, mist or gas. Avoid contact with skin, eyes and clothing. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Follow the skin protection plan. Take off all contaminated clothing immediately. Wash contaminated clothing before re-use.

Stability and reactivity

Conditions to avoid :

   Heat, flames and sparks. Exposure to sunlight. Exposure to moisture.

Materials to avoid :

   Strong oxidizing agents, Alkali metals, Alkaline earth metals

Hazardous decomposition products:

   In case of fire hazardous decomposition products may be produced such as: Carbon oxides, Hydrogen fluoride

   

Hazardous reactions :

   Vapours may form explosive mixtures with air.

Stability :

   No decomposition if stored and applied as directed.

Disposal considerations

Advice on disposal and packaging:

   Disposal:

   In accordance with local and national regulations. Do not dispose of waste into sewer. This material and its container must be disposed of as hazardous waste. Do not dispose of together with household waste. Waste codes should be assigned by the user based on the application for which the product was used.