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Environmental fate & pathways

Phototransformation in water

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Administrative data

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Description of key information

The UV/VIS spectral absorption of cloquintocet acid was determined. These data were used for calculation of the half lives of direct photochemical degradation under environmental conditions for the months March and June in Central Europe.

The absorption maxima was at 313.5 nm and decadic molar extinction coefficient was Ɛ = 3842 [l/mol/cm]at 321 nm for cloquintocet acid, respectively.

Assuming a quantum yield for the direct photolytic degradation of 1.0, half lives were calculated to be 2 minutes (March) and 1 minute (June) for cloquintocet acid. Applying a quantum yield of only 0.1, corresponding half lives for cloquintocet acid would be between 22 and 6 sunlight minutes which would mean a very rapid degradation by direct photolysis in all seasons. As a worst-case, the value of 22 minutes was chosen as the key value from the study.

Key value for chemical safety assessment

Half-life in water:
22 min

Additional information