Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 222-575-9 | CAS number: 3536-96-7
Explosiveness
Administrative data
- Endpoint:
- explosiveness
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 1 (reliable without restriction)
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 012
- Report date:
- 2012
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- other: Regulation (EC) No. 440/2008 (A.14 EXPLOSIVE PROPERTIES), UN transport regulations (UN-Test 3(a) (ii) „BAM-fallhammer“, UN-Test 3(b) (i) „BAM-friction-test“; UN-Test 1(b) „Koenen-test“ and UN-Test 2(b) „Koenen-Test“) and GHS/CLP.
- Deviations:
- no
- GLP compliance:
- no
Test material
- Reference substance name:
- Chlorovinylmagnesium
- EC Number:
- 222-575-9
- EC Name:
- Chlorovinylmagnesium
- Cas Number:
- 3536-96-7
- Molecular formula:
- C2H3ClMg
- IUPAC Name:
- chloro(ethenyl)magnesium
- Test material form:
- other: solution
- Details on test material:
- Chlorovinylmagnesium 23% in THF
Constituent 1
Results and discussion
Small-scale preliminary testsopen allclose all
- Parameter:
- other: More sensitive to shock than m-dinitrobenzene
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
- Parameter:
- other: More sensitive to friction than m-dinitrobenzene
- Remarks:
- migrated information
- Remarks on result:
- not measured/tested
- Parameter:
- other: Explosive under influence of flame
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
- Parameter:
- other: Explosive (not specified)
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
Any other information on results incl. tables
Thermal sensitivity (Koenen-Test):
| Net weight [g] | Nozzle-width [mm] | t1[s] | t2[s] | Reaction | Fragment picture |
27,0 |
20,0 | 10 | >300 | burning off | 0 |
| 27,3 | 12,0 | 11 | >300 | burning off | 0 |
| 27,1 | 8,0 | 10 | >300 | burning off | 0 |
| 27,3 | 6,0 | 11 | >300 | burning off | 0 |
| 27,7 | 6,0 | 10 | >300 | burning off | 0 |
| 27,8 | 6,0 |
10 | >300 | burning off | 0 |
| 27,7 | 2,0 | 11 | >300 | burning off | 0 |
| 27,8 | 2,0 | 10 | >300 | burning off | 0 |
| 27,3 | 2,0 | 10 |
>300 | burning off | 0 |
| 27,0 | 2,0 | 10 | >300 | burning off | 0 |
| 27,0 | 1,0 | 10 | >300 | burning off | 0 |
| 27,0 | 1,0 | 10 | >300 | burning off | 0 |
| 27,0 | 1,0 | 10 | >300 | burning off | 0 |
t1time until first reaction t1 time until main reaction 0 : nozzle unchanged
Mechanical sensitivity (impact stress):
In 6 trials with a drop weight of 10 kg and a height of 0.4 m, no reaction could be detected.
Mechanical sensitivity (friction stress):
This test could not be performed, because the solution is liquid.
Applicant's summary and conclusion
- Interpretation of results:
- non explosive
- Remarks:
- Migrated information
- Executive summary:
Regulation (EC) No. 440/2008 and directive 67/548/EEC:
The substane has no explosive properties according the consolidated version of directive 67/548/EEC Annex V, PartA; A.14.
Thermal sensitivity (Koenen-Test; Test E.1):
In none of the test ( Nozzle-width 20,12,8,6,2, and 1mm) a explosion could be detected.The
limiting diameterof the nozzle plateisconsequentlyless than 1.0mm. The breakdowntype of the nozzle was in all tests in accordance with type"O". The test result is rated as "-".Mechanical sensitivity (impact stress), BAM-drop hammer), Test 3 (a) (ii) :
When exposed to a 10kg weight from a height of 0.4 m no explosion was observed in the experiments. The result is rated as "-".
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
