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EC number: 600-034-1 | CAS number: 1001417-33-9
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Flammability
Administrative data
Link to relevant study record(s)
- Endpoint:
- flammable solids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- September 2017
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.10 (Flammability (Solids))
- Deviations:
- no
- GLP compliance:
- no
- Other quality assurance:
- other: ISO 9001
- Test procedure:
- burning rate test: preliminary screening test
- Burning time:
- 21 s
- Key result
- Test procedure:
- burning rate test over 100 mm length
- Burning time:
- 8 s
- Interpretation of results:
- Category 1 (flammable solids) based on GHS criteria
- Conclusions:
- The flammability of Zirconium, dimethyl[[2,2'''-[1,3-propanediylbis(oxy-κO)]bis[3'',5,5''-tris(1,1-dimethylethyl)-5'-methyl[1,1':3',1''-terphenyl]-2'-olato-κO]](2-)]-, (OC-6-33)-,was determined according to EC Regulation No 440/2008, Guideline A.10 [1] in accordance with European Chemicals Agency (ECHA), Guidance on information requirements and chemical safety assessment, Chapter R.7a, Endpoint specific guidance, May 2008 [2].
The test substance ignites easily.
The burning time for 100 mm was 8 seconds and hence less than 45 sec. Therefore DOC-6114 is considered as highly flammable according to EC guideline A.10. - Executive summary:
The flammability of Zirconium, dimethyl[[2,2'''-[1,3-propanediylbis(oxy-κO)]bis[3'',5,5''-tris(1,1-dimethylethyl)-5'-methyl[1,1':3',1''-terphenyl]-2'-olato-κO]](2-)]-, (OC-6-33)-,was determined according to EC Regulation No 440/2008, Guideline A.10 [1] in accordance with European Chemicals Agency (ECHA), Guidance on information requirements and chemical safety assessment, Chapter R.7a, Endpoint specific guidance, May 2008 [2].
The test substance ignites easily.
The burning time for 100 mm was 8 seconds and hence less than 45 sec. Therefore DOC-6114 is considered as highly flammable according to EC guideline A.10.
- Endpoint:
- pyrophoric solids
- Data waiving:
- study scientifically not necessary / other information available
- Justification for data waiving:
- the study does not need to be conducted because the substance is known to be stable in contact with air at room temperature for prolonged periods of time (days) and hence, the classification procedure does not need to be applied
- Interpretation of results:
- not classified based on GHS criteria
- Endpoint:
- self-heating substances / mixtures
- Data waiving:
- study scientifically not necessary / other information available
- Justification for data waiving:
- the study does not need to be conducted because the substance is a liquid
- Endpoint:
- substances / mixtures which in contact with water emit flammable gases
- Type of information:
- calculation (if not (Q)SAR)
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: worst case calculation based on maximum production of methane due to known instanteous hydrolysis of the metal-methyl bonds
- Principles of method if other than guideline:
- calculation based on maximum production of methane
- Key result
- Test procedure:
- other: calculation based on production of 2 moles of methane for 1 mole of complex within 1 minute
- Max. rate of gas release:
- 46.6 L/kg min
- Identity of evolved gas:
- as specified:
- Remarks:
- methane
- Remarks on result:
- vigorous reaction with water and spontaneous ignition of the evolved gas
- Interpretation of results:
- Category 1 (substances or mixtures which in contact with water release flammable gases which may ignite spontaneously) based on GHS criteria
- Conclusions:
- Maximum expectable gassing rate for DOC-6114 is 46.6 L/kg/minute
- Executive summary:
Maximum expectable gassing rate for DOC-6114 is 46.6 L/kg/minute
Referenceopen allclose all
In the screening test the gas flame was applied to one end of the substance strip.
The substance ignited easily.
The time for burning 200 mm of the powder train was 21 seconds. This is within the test period of 4 minutes and therefore the burning rate test was performed.
The burning rate test was performed 1 time. The burning time for 100 mm was 8 seconds.
This result (burning time over 100 mm < 45 seconds) means that the substance is considered as highly flammable according to EC guideline A.10.
Description of key information
The substance is a highly flammable solid. The substance is not pyrophoric. The substance reacts with water to emit flammable gases (methane).
Key value for chemical safety assessment
- Flammability:
- flammable
Additional information
Justification for classification or non-classification
The substance is a highly flammable solid. The substance is not pyrophoric. The substance reacts with water to emit flammable gases (methane).
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