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Diss Factsheets
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EC number: 236-152-1 | CAS number: 13194-48-4
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Take off immediately all contaminated clothing. In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Wash contaminated clothing before reuse. Discard any shoes or clothing items that cannot be decontaminated. This product is a Cholinesterase Inhibitor. A physician should be contacted in all cases of exposure to the technical and its formulations.
Description of first aid measures
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician or poison control centre immediately.
Skin contact:
Remove contaminated clothing immediately and wash skin with soap and water. Call a physician or poison control centre immediately. Wash contaminated clothing before reuse.
Eye contact:
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control centre immediately.
Ingestion:
Call a physician or poison control centre immediately. Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important symptoms and effects, both acute and delayed
May cause an allergic skin reaction. Dermatitis. Rash. Acute cholinesterase depression may be evidenced by headache, nausea, vomiting, diarrhea, abdominal cramps, excessive sweating, salivation and tearing, constricted pupils, blurred vision, tightness in chest, weakness, muscle twitching and confusion; in extreme cases, unconsciousness, convulsions, severe respiratory depression and death may occur. Product may cause slight but temporary irritation to the eyes and may cause irritation of the skin.
Indication of any immediate medical attention and special treatment needed
In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. This is a cholinesterase inhibiting organophosphorous pesticide. Monitor respiratory, cardiac and central nervous system. Monitor red blood cell and plasma cholinesterase. In case of convulsions, a benzodiazepine (e.g. diazepam) should be given according to standard regimens. The following antidotes are generally accepted: atropine and oximes.
Fire-fighting measures
General fire hazards
No unusual fire or explosion hazards noted.
Extinguishing media
Suitable extinguishing media:
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing media:
Do not use water jet as an extinguisher, as this will spread the fire.
Special hazards arising from the substance or mixture
During fire, gases hazardous to health may be formed.
Advice for firefighters
Special protective equipment for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Special fire-fighting procedures
Move containers from fire area if you can do so without risk.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not breathe vapours or spray mist. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained.
For emergency responders
Keep unnecessary personnel away. Use personal protection as recommended in the SDS.
Environmental precautions
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.
Methods and material for containment and cleaning up
Prevent product from entering drains.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Siphon the majority of the liquid into drums for use or disposal, depending on the circumstances. Clean the area as described for a small spill.
Small Spills: Absorb in vermiculite, dry sand or earth and place into containers. Scrub contaminated area with detergent and bleach solution. Absorb cleanup materials with inert absorbent and sweep into the same disposal drum used for the small spill. Close the drum and dispose as a hazardous waste.
Never return spills to original containers for re-use.
Handling and storage
Precautions for safe handling
Do not breathe vapours or spray mist. Do not get in eyes, on skin, or on clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Wash contaminated clothing before reuse. Observe good industrial hygiene practices.
Conditions for safe storage, including any incompatibilities
Store locked up. Store in original tightly closed container. Store in a well-ventilated place.
Specific end use(s)
Technical grade pesticide for use in preparation of formulated products.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN3018
Shipping information
- Proper shipping name and description:
- Organophosphorus pesticide, liquid, toxic (Ethoprophos)
- Language:
- English
- Class or division:
- Class 6: Toxic and infectious substances; Division 6.1
- Packing group:
- Packing group I: Substances presenting high danger
- Labels:
- 6.1
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN3018
Shipping information
- Proper shipping name and description:
- Organophosphorus pesticide, liquid, toxic (Ethoprophos)
- Language:
- English
- Class or division:
- Class 6: Toxic and infectious substances; Division 6.1
- Packing group:
- Packing group I: Substances presenting high danger
- Labels:
- 6.1
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN3018
Shipping information
- Proper shipping name and description:
- ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC (Ethoprophos), MARINE POLLUTANT
- Language:
- English
- Class or division:
- Class 6: Toxic and infectious substances; Division 6.1
- Packing group:
- Packing group I: Substances presenting high danger
- EmS code:
- F-A
- S-A
- Labels:
- 6.1
- Marine pollutant
Special provisions / remarks
- Special provisions:
- Read safety instructions, SDS and emergency procedures before handling.
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN3018
Shipping information
- Proper shipping name and description:
- Organophosphorus pesticide, liquid, toxic (Ethoprophos)
- Language:
- English
- Class or division:
- Class 6: Toxic and infectious substances; Division 6.1
- Packing group:
- Packing group I: Substances presenting high danger
- Labels:
- 6.1
Special provisions / remarks
- Special provisions:
- Read safety instructions, SDS and emergency procedures before handling.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
General information
Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment.
Eye/face protection
Wear safety glasses with side shields (or goggles). Chemical goggles and face shield are recommended. Wear a full-face respirator, if needed.
Skin protection
Hand protection
Wear appropriate chemical resistant gloves. Nitrile gloves are recommended, but be aware that the liquid may penetrate the gloves. Frequent change is advisable.
Other
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. The following clothing is required: overalls or pants and long-sleeved shirt, chemical resistant gloves (preferably nitrile), chemical resistant boots. For added protection a chemical resistant apron and a full face shield are recommended. It there is a risk of splashing, misting or release the following additional PPE is required: two piece hooded chemical resistant suit with either a full face respirator or a SCBA. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions are available, use detergent and hot water. Keep and wash PPE separately
Respiratory protection
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
Hygiene measures
Keep away from food and drink. When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace.
Environmental exposure controls
Contain spills and prevent releases and observe national regulations on emissions.
Stability and reactivity
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous reactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid
Avoid temperatures exceeding the decomposition temperature. Contact with incompatible materials.
Incompatible materials
Alkali metals. Isocyanates.
Hazardous decomposition products
Emits hazardous fumes and smoke of unknown composition when heated to decomposition or burned.
Disposal considerations
Waste treatment methods
Residual waste
Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
EU waste code
The Waste code should be assigned in discussion between the user, the producer and the waste disposal company.
Disposal methods/information
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. This material and its container must be disposed of as hazardous waste. Dispose of contents/container in accordance with local/regional/national/international regulations.
Special precautions
Dispose in accordance with all applicable regulations
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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