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Diss Factsheets

Physical & Chemical properties

Stability: thermal, sunlight, metals

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
stability: thermal, sunlight, metals, other
Type of information:
experimental study
Adequacy of study:
key study
Study period:
January 30, 2012 - February 02, 2012
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 113 (Screening Test for Thermal Stability and Stability in Air)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Test substance thermally stable:
no
Key result
Operating temp.:
>= 0 - <= 360 °C
Sublimation:
no
Transformation products:
not measured
Test substance stable to sunlight:
not determined
Test substance stable to metals / metal ions:
not determined

The test item BKC showed a first endothermic effect in the temperature range 30 – 45 °C and a second in the temperature range of 165 – 210 °C. The first endothermic effect is related to the melting point, see below. In the temperature range of 300 – 355 °C an exothermal effect could be observed.

Conclusions:
Under the study conditions, test substance showed two endothermic effects, the first at the temperature range 30 – 45°C and the second at the temperature range 165 – 210°C, whereas it showed an exothermal effect in the temperature range of 300 – 355°C.
Executive summary:

A study was conducted to determine the thermal stability of the test substance, C12-16 ADBAC (purity: 99.2%) according to the OECD Guideline 113, using differential scanning calorimetry. The crucibles were heated up from 0°C to 360°C with a heating rate of 3 K/min in a nitrogen atmosphere. Under the study conditions, test substance showed two endothermic effects, the first at the temperature range 30 – 45°C and the second at the temperature range 165 – 210°C, whereas it showed an exothermal effect in the temperature range of 300 – 355°C (Moller, 2012).

Description of key information

The thermal stability was determined using the DSC method according to the OECD Guideline 113 (Moller, 2012)

Additional information

The test substance showed two endothermic effects, the first at the temperature range 30 – 45 ° and the second at the temperature range 165 – 210 °C.

Justification for classification or non-classification