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EC number: 268-453-9 | CAS number: 68092-29-5
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Flash point
Administrative data
- Endpoint:
- flash point of flammable liquids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- from 18 Sep 2017 to 07 Nov 2017
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- test procedure in accordance with generally accepted scientific standards and described in sufficient detail
Cross-reference
- Reason / purpose for cross-reference:
- reference to other study
Reference
- Endpoint:
- melting point/freezing point
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- from 18 Sep 2017 to 07 Nov 2017
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.1 (Melting / Freezing Temperature)
- Version / remarks:
- 2008
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 102 (Melting point / Melting Range)
- Version / remarks:
- 1995
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- EPA OPPTS 830.7200 (Melting Point / Melting Range)
- Version / remarks:
- 1998
- Deviations:
- no
- GLP compliance:
- yes
- Type of method:
- differential scanning calorimetry
- Key result
- Decomposition:
- yes
- Decomp. temp.:
- 100 °C
- Remarks on result:
- other: glass transition between -64.2°C and -66.5°C and glass transition between -16.0°C and -17.6°C. No melting/freezing point was determined between 25°C and -90°C.
- Conclusions:
- A glass transition range between -64.2°C and -66.5°C and a second glass transition range between -16.0°C and -17.6°C were determined.
The substance has no melting/freezing temperature between 25°C and -90°C. - Executive summary:
Differential Scanning Calorimetry (DSC) experiments were performed in a GLP study according to EC A.1, OECD 102 and OPPTS 830.7200.
The liquid substance has no melting/freezing temperature between 25°C and -90°C. From triplicate measurements, a glass transition range between -64.2°C and -66.5°C and a second glass transition range between -16.0°C and -17.6°C were determined.
During heating from -90°C to 368°C reaction and/or decomposition of the substance started at 100°C.
NOTE: Any of data in this dataset are disseminated by the European Union on a right-to-know basis and this is not a publication in the same sense as a book or an article in a journal. The right of ownership in any part of this information is reserved by the data owner(s). The use of this information for any other, e.g. commercial purpose is strictly reserved to the data owners and those persons or legal entities having paid the respective access fee for the intended purpose.
TGA EXPERIMENT (PRELIMINARY TEST)
Significant decrease of weight from 125°C. 25% weight loss at 368°C and 70% weight loss at 420°C.
After the experiment, a dark brown residue remained in the sample container. The change of the colour indicated reaction and/or decomposition of the test item.
DSC EXPERIMENT 1
During cooling a glass transition was observed between-60°C and -80°C.
During heating a glass transition was observed between -75°C and -50°C (inflection point: -65.447°C) and a second glass transition was observed between -50°C and 0°C (inflection point: -16.154°C).
From 100°C an exothermic effect was observed. After the experiment, a dark brown molten residue remained in the sample container (original colour: amber). The exothermic effect was most probably obtained due to reaction and/or decomposition of the test item.
DSC EXPERIMENT 2
Similar results as in Experiment 1 were obtained. Inflection points of the glass transitions: -66.472°C and -17.639°C.
DSC EXPERIMENT 3
The difference in the inflection point between Experiment 1 and Experiment 2 was > 0.5°C. Therefore Experiment 3 was performed using the same temperature program.
First inflection point: -64.155°C; second inflection point: -16.039°C. After the experiment, a dark brown molten residue remained in the sample container.
DATA HANDLING
The first glass transition point obtained from Experiment 1 (-65.447°C), Experiment 2 (-66.472°C) and Experiment 3 (-64.155°C) and the second glass transition point obtained from Experiment 1 (-16.154°C), Experiment 2 (-17.639°C) and Experiment 3 (-16.039°C) are reported as a range, as the inflection points differed significantly.
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 018
- Report date:
- 2018
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- EU Method A.9 (Flash-Point)
- Version / remarks:
- 2008
- Qualifier:
- according to guideline
- Guideline:
- other: ASTM D7094: “Standard Test Method for Flash Point by Modified Continuously Closed Cup (MCCCFP) Tester”
- Version / remarks:
- 2012
- Deviations:
- not specified
- Principles of method if other than guideline:
- According to ECA.9 the flash point can be determined by an equilibrium method or a non-equilibrium method. Several methods are mentioned in the guideline. ASTM D7094 is not one of the methods mentioned in the guideline but is a commonly used and safer (low sample volume) alternative for the non-equilibrium ISO 2719 Pensky martens closed cup method.
- GLP compliance:
- yes
- Type of method:
- other: modified continuously closed cup
- Flash point apparatus:
- other: Eraflash (Eralytics, Austria)
- Dynamic viscosity of test material:
- no data
Test material
- Reference substance name:
- Tall oil, compd. with triethanolamine
- EC Number:
- 268-453-9
- EC Name:
- Tall oil, compd. with triethanolamine
- Cas Number:
- 68092-29-5
- Molecular formula:
- Various
- IUPAC Name:
- Tall oil, compd. with triethanolamine
- Test material form:
- liquid
- Details on test material:
- Appearance: Amber liquid
Storage conditions: At room temperature
Constituent 1
- Specific details on test material used for the study:
- No boiling before decomposition.
Results and discussion
Flash point
- Key result
- Atm. press.:
- 1 013 hPa
- Remarks on result:
- no flash point up to 100°C
Any other information on results incl. tables
No flammable vapour/air mixture was produced at temperatures below the temperature at which reaction and/or degradation of the test item occurred.
Applicant's summary and conclusion
- Interpretation of results:
- other: not classified under CLP or GHS
- Conclusions:
- No flash point before decomposition.
- Executive summary:
The modified continuously closed cup ASTM D7094 method (GLP study) was performed. In duplicate tests it was found that the substance has no flash point before decomposition. The decomposition temperature of the substance has been determined in a DSC study to be 100°C.
NOTE: Any of data in this dataset are disseminated by the European Union on a right-to-know basis and this is not a publication in the same sense as a book or an article in a journal. The right of ownership in any part of this information is reserved by the data owner(s). The use of this information for any other, e.g. commercial purpose is strictly reserved to the data owners and those persons or legal entities having paid the respective access fee for the intended purpose.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.