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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 203-981-5 | CAS number: 112-52-7
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
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Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures:
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation
Potential for exposure by inhalation if aerosols or mists are generated.
After inhalation move subject to fresh air.
With labored breathing: Provide with oxygen. Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact
Wash off affected area immediately with plenty of water.
Continue decontamination with polyethylene glycol 400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.
Eye contact
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
Ingestion
Rinse mouth.
Immediately give large quantities of water to drink.
Obtain medical attention.
Most important symptoms and effects, both acute and delayed:
Symptoms
Irritation of skin and mucous membranes
Hazards
irritant effects
Indication of any immediate medical attention and special treatment needed:
The initial focus is only on the local action, possibly characterized by a progressive tissue irritation.
Coughing is a symptom of a respiratory tract irritation after inhalation of aerosols or mists from caustic liquids.
In the eye, irritating liquids cause, depending on the intensity of exposure, irritation of the conjunctiva and, in exceptional cases, damage to the cornea.
There is a danger of blindness if corneas are damaged!
Superficial irritations and only infrequent damage with ulcerations develop on the skin.
An irritation of the mucous membranes may develop and lead to coughing after inhalation.
Fire-fighting measures
Extinguishing media:
Suitable extinguishing media: Water spray, foam, CO2, dry powder.
Unsuitable extinguishing media: high volume water jet
Special hazards arising from the substance or mixture:
Hazardous fumes in fires, specific to the product:
hydrochloric acid
Carbon oxides
Under certain fire conditions, traces of other toxic products may occur.
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
Use water spray to cool unopened containers.
Fire residues should be disposed of in accordance with the regulations.
Pay attention to self-protection.
Keep out unprotected persons.
In case of fire: full protective suit and wear a self contained respiratory apparatus
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Keep unauthorized persons away
Environmental precautions:
Observe regulations on prevention of water pollution (check, dam up, cover up).
Do not allow entrance in sewage water, soil, stretches of water, drainage systems, surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material, e. g.: chemisorption, diatomaceous earth, universal binder
Transfer into suitable containers.
Clean contaminated surface thoroughly.
Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.
Disposal according to local authority regulations.
Handling and storage
Precautions for safe handling:
Use permissible in closed systems only. Handle and transfer product in closed systems only (gas displacement device).
Ensure that apparatus and pipelines are free from leaks. Do not ventilate into the open.
Suitable loading and unloading device required.
Conditions for safe storage, including any incompatibilities:
Advice on protection against fire and explosion
Normal measures for preventive fire protection.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Storage
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
Suitable materials stainless steel
Unsuitable materials Light metals, copper, brass
Observe prohibition against storing together!
Further information
Protect from sunlight, warmth and heat.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.
In the event of internal transportation, already-opened containers are to be kept closed in order to avoid spillage.
German storage class
Combustible / non-combustible liquids and solids not assigned to other storage classes.
Specific end use(s):
We are unaware of any specific end uses which go beyond the data reported in Section 1 SDS.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3082
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3082
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (1-chlorododecane)
- Chemical name:
- 1-chlorododecane
- Labels:
- 9
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, liquid, n.o.s. (1-chlorododecane)
- Chemical name:
- 1-chlorododecane
- Labels:
- 9MI
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters
DNEL/DMEL values
Remarks No substance-related safety assessment is necessary / has been conducted for this product.
PNEC values Remarks No substance-related safety assessment is necessary / has been conducted for this product.
Exposure controls:
Engineering measures
Refill and handle product only in closed system.
Leak detection recommended
Wastewater can be added to a biological wastewater treatment plant.
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
Dispose of waste gases in a suitable incineration plant.
All precautionary measures indicated have to be observed.
Exposure controls
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.
Personal protective equipment
Respiratory protection
Accidental release measures
use respiratory equipment with suitable filter (filter type P3) or wear a self contained respiratory apparatus
Note time limit for wearing respiratory protective equipment.
Hand protection
Accidental release measures
Glove material Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness 0,65 mm
Method DIN EN 374
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to EN 374 due to the many different influential factors involved (e.g. temperature).
Eye protection
Safety glasses with side-shields conforming to EN166
Skin and body protection
Select materials and equipment for physical protection depending on the concentration and volume of hazardous substances and the workplace involved.
Hygiene measures
Remove and wash contaminated clothing before re-use.
Do not eat, drink, smoke, or sniff while at work. Wash your hands and/or face before breaks and before termination of work.
Preventive skin protection is recommended.
Use barrier cream regularly.
Protective measures
All precautionary measures indicated have to be observed.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
Regular safety training is a must.
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.
Environmental exposure controls
In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease emissions to acceptable values.
Stability and reactivity
Reactivity:
No further information available
Chemical stability:
Stable under recommended storage conditions.
Possibility of hazardous reactions:
Possibility of hazardous reactions No dangerous reaction known under conditions of normal use.
Conditions to avoid:
sun rays, heat, heat effect
Incompatible materials:
No further information available
Hazardous decomposition products:
Decomposition products in combustion and thermal decomposition
carbon monoxide, carbon dioxide
organic products of decomposition
hydrogen chloride
Disposal considerations
Waste treatment methods:
Product
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Wastewater can be added to a biological wastewater treatment plant.
Bring wastewater containing AOX for professional disposal.
Disposal according to local authority regulations.
Uncleaned packaging
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
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