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Physical & Chemical properties

Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Study initiation date: 24 June 2009 Study completion date: 28 October 2009
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Qualifier:
according to guideline
Guideline:
other: DIN 51 794 (covers a temperature range from 75 to 650 °C)
Principles of method if other than guideline:
One of the possible methods referred to within EU method A.15 is DIN 51794 ("Testing of mineral oil hydrocarbons - Determination of ignition temperature"
GLP compliance:
yes
Auto-ignition temperature:
215 °C
Atm. press.:
1 001 hPa
Remarks on result:
other:

Details on single measurements:

  Temperature [°C] Injected volume Time-lag [s] until
[Drops] ignition
Test 1 240 5 5
235 5 14
230 5 12
225 5 / 10 - / 24
220 10 30
215 10/15 /20 - / - / -
218 20 43
216 20 -

  Temperature [°C] Injected volume Time-lag [s] until
[Drops] ignition
Test 2 230 5 14
225 5 / 10 - / 15
220 10 26
215 10 /15 /20 - / - / -
218 20 36
216 20 45
214 20 -
-- -- --

  Temperature [°C] Injected volume Time-lag [s] until
[Drops] ignition
Test 3 230 5 14
225 5 / 10 - / 19
220 10 33
215 10/15/20 - / - / -
218 20 31
216 20 46
214 20 -
-- -- --

The measured lowest ignition temperatures of the main test are <300 °C and do not differ by more than 10 °C, thus the test is satisfactory.

The auto-ignition temperature is defined as the lowest temperature of all single results of the main test, but rounded down to multiples of 5 °C.

Test 1 Test 2 Test 3
Lowest ignition temperatures [°C] 218 216 216
Auto-ignition temperature [°C] 215
Conclusions:
Auto-ignition temperature = 215 °C
Executive summary:

The auto-ignition temperature of the test item was determined according to EU test method A.15 [Directive 92/69/EEC, Official Journal L 383 A 1992]

Auto-ignition temperature: (1001 hPa) 215 °C

Description of key information

The auto-ignition temperature of the test item was determined according to EU test method A.15 [Directive 92/69/EEC, Official Journal L 383 A 1992]
Auto-ignition temperature: (1001 hPa) 215 °C

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
215 °C

Additional information

The auto-ignition temperature of the test item was determined according to EU test method A.15 [Directive 92/69/EEC, Official Journal L 383 A 1992] Auto-ignition temperature: (1001 hPa) 215 °C.

According to (1), the phenomenon of self-heating applies only to solids, liquids are not classified as self-heating. Thus, no classification requirements are associated with this result.

(1) Guidance on the Application of the CLP Criteria; ECHA-13-G-10-EN, November 2013