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Diss Factsheets
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EC number: 700-268-5 | CAS number: 18143-33-4
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Move to fresh air, keep the victim laying down and restful. If breathing has stopped, give artificial respiration. Administer oxygen in case of breathing difficulties. Seek medical advice and clearly identify substance.
After contact with the skin:
Wash with plenty of water or soap and water; immediately remove all contaminated clothing. In cases of sickness seek medical advice (show label if possible).
After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes and seek medical advice.
After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and produce the label or packaging.
Advice for the physician:
In case of contact with water material splits off (also in gastrointestinal tract) methanol in larger amounts; therefore consider poisoning on methanol and also observe known period of latency of several days!
Fire-fighting measures
water mist, extinguishing powder, alcohol-resistant foam, carbon dioxide, sand.
Extinguishing media which must not be used for safety reasons:
water spray, water jet.
Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases:
Hazardous combustion products: hydrogen chloride
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air.
Accidental release measures
Wear personal protection equipment (see section 8). Keep unprotected persons away. Avoid contact with eyes and skin. Avoid inhaling mists and vapours. If material is released indicate risk of slipping.
Environmental precautions:
Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers.
Methods for cleaning up:
Do not flush away with water. For small amounts: Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations. Contain larger amounts and pump up into suitable containers. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. Exhaust vapours.
Further information:
Eliminate all sources of ignition.
Handling and storage
Avoid exposure by technical measures or personal protective equipment.
Handling
Precautions for safe handling:
Ensure adequate ventilation. Keep away from incompatible substances in accordance with section 10.2. Spilled substance increases risk of slipping.
Precautions against fire and explosion:
Product can separate methanol. Vapours may form in closed rooms with air mixtures, leading to explosion in the presence of sources of ignition, even in empty, uncleaned vessels. Keep away from sources of ignition and do not smoke. Take precautionary measures against electrostatic charging. Cool endangered containers with water.
Storage
Conditions for storage rooms and vessels:
Unsuitable material for storage containers, casks and pipelines: steel , aluminum , synthetics .
Advice for storage of incompatible materials:
not applicable
Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated place.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- Entzündbarer flüssiger Stoff, n.a.g.
- Chemical name:
- ((Chlormethyl)methoxydimethylsilan)
- Language:
- German
- Labels:
- entzündbare Flüssigkeit/3
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- Entzündbarer flüssiger Stoff, n.a.g.
- Chemical name:
- ((Chlormethyl)methoxydimethylsilan)
- Language:
- German
- Labels:
- entzündbare Flüssigkeit/3
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- Flammable liquid, n.o.s.
- Chemical name:
- ((Chloromethyl)methoxydimethylsilane)
- Labels:
- flammable liquid /3
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- Flammable liquid, n.o.s.
- Chemical name:
- ((Chloromethyl)methoxydimethylsilane)
- Labels:
- flammable liquid /3
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Maximum airborne concentrations at the workplace:
CAS No. Material Type mg/m3 ppm Dust fract. Fibre/m3
67-56-1 Methanol occupational exposure limit 270,0 200,0
BAT-Value:
CAS No. Material Param. Value other material Time
67-56-1 METHANOL 30 mg/l URIN C,B
Exposure limited and controlled
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.
Personal protection equipment
Respiratory protection:
In case of long or strong exposure: gas mask filter ABEK .
Hand protection:
Protective gloves made of butyl rubber or PVC Gloves suitable for up to 60 minutes' use.
Eye protection:
tight fitting protective goggles .
Skin protection:
protective clothing.
Exposure to the environment limited and controlled:
Prevent material from entering surface waters and soil.
Stability and reactivity
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Conditions to avoid:
none known
Materials to avoid:
Reacts with water, basic substances or acids. Reaction causes the formation of methanol.
Hazardous decomposition products:
If stored and handled in accordance with standard industrial practices and local regulations where applicable: none known. Under the effect of humidity, water and protic agents methanol.
Disposal considerations
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local/state/federal regulations.
Waste Disposal Legislation Ref.No.(EC):
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison with the waste-disposal operator.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.