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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
oxidising properties, other
Type of information:
experimental study
Adequacy of study:
key study
Study period:
23.07.2012 - 07.08.2012
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
other:
Principles of method if other than guideline:
Redox titrations are based on a reduction-oxidation reaction between an oxidizing agent and a reducing agent. A potentiometer or a redox indicator is usually used to determine the endpoint of the titration. In permanganometry a slight faint persisting pink color signals the endpoint of the titration because of the color of the excess oxidizing agent potassium permanganate
GLP compliance:
no
Specific details on test material used for the study:
- Name of test material (IUPAC name): Benzyl propionate
- Molecular formula: C10H12O2
- Molecular weight: 164.203 g/mol
- SMILES: c1(COC(CC)=O)ccccc1
- InChI: 1S/C10H12O2/c1-2-10(11)12-8-9-6-4-3-5-7-9/h3-7H,2,8H2,1H3
- Substance type: Organic
- Physical state: Liquid
- Batch: 2014030601 R-87
- Purity: 99.79% (GLC)
- Physical Appearance: Colourless liquid
- Stability: Stable in recommended storage conditions
- Storage Conditions: Store in cool, dry and ventilated area away from heat sources and protected from light in tightly closed original container. Keep air contact to a minimum.
Contact with:
potassium permanganate
Key result
Sample tested:
other: not specified (migrated information) ml or mg of KMnO4
Parameter:
other: ml or mg of KMnO4
Result:
121.5 other: ml/100g
Remarks on result:
other: No other detail available
Interpretation of results:
other: oxidising
Conclusions:
Benzyl propionate was found to have mild oxidising property since 121.5 ml of KMnO4 was required for getting the end point of the redox titration for 100 g of Benzyl propionate.
Executive summary:

Benzyl propionate was found to have mild oxidising property since 121.5 ml of KMnO4 was required for getting the end point of the redox titration for 100 g of Benzyl propionate. This oxidation potential was not considered strong enough for for classifying the chemical as an oxidising liquid.Thus, the chemical is considered as non-oxidising for the purpose of chemical safety report and classification.

Description of key information

Benzyl propionate was found to have mild oxidising property since 121.5 ml of KMnO4 was required for getting the end point of the redox titration for 100 g of Benzyl propionate.

Key value for chemical safety assessment

Oxidising properties:
yes

Additional information

Benzyl propionate was found to have mild oxidising property since 121.5 ml of KMnO4 was required for getting the end point of the redox titration for 100 g of Benzyl propionate. This oxidation potential was not considered strong enough for for classifying the chemical as an oxidising liquid.Thus, the chemical is considered as non-oxidising for the purpose of chemical safety report and classification.

Justification for classification or non-classification

Benzyl propionate was found to have mild oxidising property since 121.5 ml of KMnO4 was required for getting the end point of the redox titration for 100 g of Benzyl propionate. This oxidation potential was not considered strong enough for for classifying the chemical as an oxidising liquid.Thus, the chemical is considered as non-oxidising for the purpose of chemical safety report and classification.