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Diss Factsheets
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EC number: 213-947-1 | CAS number: 1068-55-9
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Explosiveness
Administrative data
- Endpoint:
- explosiveness
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2015-09 to 2015-11
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: Guidance compliant study on another Grignard substance
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 015
- Report date:
- 2015
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- according to guideline
- Guideline:
- other: Test 1 (c), 2 (c) and C.1 of the „UN Recommendations on Transport of Dangerous Goods - Manual of Test and Criteria“, Time-pressure-test, 5th revised edition
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- other: Test 1 (b), 2 (b) and E.1 of the „UN Recommendations on Transport of Dangerous Goods - Manual of Test and Criteria“, Koenen-test, 5th revised edition
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- other: Test F.3 of the „UN Recommendations on Transport of Dangerous Goods - Manual of Test and Criteria“, Trauzl-test, 5th revised edition
- Deviations:
- no
- GLP compliance:
- no
Test material
- Reference substance name:
- Methylmagnesium chloride
- EC Number:
- 211-629-7
- EC Name:
- Methylmagnesium chloride
- Cas Number:
- 676-58-4
- IUPAC Name:
- methylmagnesium(1+) chloride
- Test material form:
- other: Methylmagnesium chloride, ca. 22 % in THF
Constituent 1
Results and discussion
Small-scale preliminary tests
- Parameter:
- other: Explosive (not specified)
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
Any other information on results incl. tables
Time-pressure-test: None of the three tests reached a pressure of 2070 kPa. Therefore the result has to be evaluated as negative.
Koenen-test: The tube remained unchanged. The results have to be evaluated as negative.
Trauzl-test (performed and evaluated by the BAM, sign 2.2-114/15): The increased volume was 5 ml and 6 ml per 10 g of sample. Due to the fact that the volume expansion of the cavity in the lead block was less than 10 ml per 10 g sample the results have to be evaluated as negative.
Applicant's summary and conclusion
- Interpretation of results:
- non explosive
- Remarks:
- Migrated information
- Conclusions:
- Due to the results presented in this report from the UN-tests 1(b) (effect of heating under confinement; Koenen-test), 1(c) (effect of ignition under confinement; Time-pressure-test) and F.3 (Trauzl-test; substitute test for 1(a) (propagation of detonation) of the „UN Recommendations on Transport of Dangerous Goods - Manual of Test and Criteria“ it can be concluded that the substance is not explosive.
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