Registration Dossier
Registration Dossier
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Diss Factsheets
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EC number: 203-067-6 | CAS number: 102-97-6
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Description of first aid measures
In case of inhalation: Move the victim to fresh air and keep him or her at rest. If breathing is difficult, administer oxygen by an authorised person. Seek medical advice if the effects continue.
In case of contact with skin: Remove contaminated clothing and shoes immediately. Rinse affected skin with plenty of soap and water. Seek medical advice if irritation continues.
In case of contact with eyes: In case of eye contact, rinse with plenty of water for at least 15 minutes. Ensure adequate rinsing of the eyes by separating the eyelids with your fingers. Seek medical advice if necessary.
In case of ingestion: If swallowed, rinse the mouth with water if the person is conscious. Do not induce vomiting and drink 2-4 tablespoons of milk or water. Obtain medical attention.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Use sand, foam, dry chemicals or carbon dioxide.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
It can produce toxic fumes of carbon monoxide and nitrogen dioxide and oxides of nitrogen on combustion. No hazardous polymerisation occurs.
ADVICE FOR FIREFIGHTERS
For individual units (drum): No special requirements. For large quantities (several drums/pallets) of product: Toxic, corrosive or flammable vapours may evolve from fires involving the product and associated packaging, and therefore a breathing apparatus (full-face mask with "Universal" filter) and full protective equipment are recommended for firefighters. If possible, contain and collect water used in the fire for subsequent disposal. Water sprays can be used to cool closed containers.
Accidental release measures
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
• Prevention of skin and eye contact and personal clothing: wear protective clothing, protective glasses, rubber boots and heavy-duty rubber gloves.
• Removal of ignition sources: not applicable
• Provision for sufficient ventilation/ respiratory protection: wear an independent respirator. Evacuate the area and aerate the zone contaminated by the spilt product after cleaning it away completely.
• Control of dust: avoid forming clouds of dust/powder.
ENVIRONMENTAL PRECAUTIONS
Do not allow the product to enter water or the soil. Prevent it from entering the drains or sewers. Use suitable containers for preventing environmental pollution. Alert neighbourhood: not necessary.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
• Use of absorbent material: vermiculite, dry sand, earth.
• Cleaning methods: use suitable personal protection. Clean only under expert supervision. Remove the product by mechanical means (hoover protected against discharge Remove by mechanical means (vacuum cleaner protected from electric shock) or with a wet brush; recover the product where possible by collecting it in clean containers for reuse or disposal. Wash the area contaminated by the product with water after it has been completely recovered. Ventilate the environment. Seal and label containers. Remove contaminated materials. Do not pour product down drains. Use appropriate containers to avoid environmental pollution. Hand containers to waste disposal personnel.
Handling and storage
PRECAUTIONS FOR SAFE HANDLING
• Containment, local and general ventilation, measures to prevent aerosol and dust generation and fire: the premises set up for the handling of the product must be fitted out with localised and controlled aeration systems (laminar
flow hoods, etc.) capable of confining the dispersion of the active ingredient in the form of air-dispersed powder. Use hoods with interchangeable filters
• Prevent handling of incompatible substances or mixtures: not applicable
• Advice on general occupational hygiene: use suitable personal protection devices including certified respirators, protective safety glasses and compatible gloves resistant against chemical agents. Wash yourself with care after each handling operation. Never eat, drink or smoke during handling. Safety shower and washing stations for rinsing eyes must be provided.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
• Specific storage requirements to manage risks associated: N.D.
• Specific storage requirements to control of the environmental effects: store in a dry, well-ventilated place at room temperature. Keep container tightly closed when not in use or empty.
• Ventilation requirements: N.D.
• Specific design for storage rooms or vessels: N.D.
• Type of materials used in packing/containers of substance: packaging the product in HDPE - HM plastic drums
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not classified as hazardous for land (ADR/RID/RMP), sea (IMO) or air (IATA) transport.
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
INDIVIDUAL PROTECTION MEASURES SUCH AS PERSONAL PROTECTIVE EQUIPMENT
- EYE/ FACE PROTECTION Tightly fitting safety glasses. Protective visor (minimum 20 cm). Use eye protection equipment tested and approved according to the requirements of appropriate technical standards such as NIOSH (USA) or EN 166 (EU)
- SKIN PROTECTION Use work overalls and/or coat, or dustproof overalls in Tyvek with hood for industrial type operations.
- HAND PROTECTION
- Type of material and thickness Handle with nitrile or nitrile rubber (neoprene) gloves. Gloves should be checked before use. Use proper glove removal technique (without touching the outer surface of the glove) to avoid skin contact with this product Dispose of contaminated gloves after use in accordance with current regulations and good laboratory practice. Wash and dry hands. Minimum thickness: 0.11 mm (nitrile).
- Typical or minimum breakthrough times of the glove material: Splash contact Material: butyl rubber. Minimum thickness: 0.7 mm . Penetration time: > 30 min.
- RESPIRATORY PROTECTION: if the risk assessment indicates the need for air-purifying respirators, use a full-face mask with ABEK (EN 14387) type combination filters as an aid to technical measures. If the respirator is the only means of protection, use a ventilated full-face system. Use respirators and components tested and approved by the relevant standardisation bodies, such as NIOSH (USA) CEN (EU).
- THERMAL HAZARDS: not applicable
ENVIRONMENTAL EXPOSURE CONTROLS: avoid dispersion in the environment.
Stability and reactivity
REACTIVITY: N.D.
CHEMICAL STABILITY: stability studies show that the product is stable at room
temperature under normal storage conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: no hazardous polymerisations occur.
CONDITIONS TO AVOID: heat, sparks, flames, direct sunlight.
INCOMPATIBLE MATERIALS: acids, Acid chlorides, Acid anhydrides, Strong oxidising agents, Carbon dioxide (CO2)
HAZARDOUS DECOMPOSITION PRODUCTS: hazardous decomposition or combustion products: Carbon monoxide, carbon dioxide and nitrogen oxides
Disposal considerations
WASTE TREATMENT METHODS
• INCINERATION This combustible product can be burnt in a chemical incinerator equipped with an afterburner and abatement system. Return non-recyclable and surplus solutions to an authorised waste disposal company.
• RECYCLING: N.A.
• DISPOSAL IN DUMP: N.D.
- DISPOSAL METHODS SUITABLE FOR THE SUBSTANCE: this material and its containers must be disposed of as hazardous waste products.
- SUITABLE DISPOSAL METHODS FOR COMBINED PACKAGING MATERIALS:
the combined packaging materials must be disposed of as hazardous waste products.
Work in compliance with the national and local laws in force.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.