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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
14/02/2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2018
Report date:
2018

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Test O.1 (Test for oxidizing solids)
Version / remarks:
2009
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
Trizirconium monoxide
Molecular formula:
Zr3O
IUPAC Name:
Trizirconium monoxide
Constituent 2
Chemical structure
Reference substance name:
Zirconium dioxide
EC Number:
215-227-2
EC Name:
Zirconium dioxide
Cas Number:
1314-23-4
Molecular formula:
O2Zr
IUPAC Name:
Zirconium dioxide
impurity 1
Chemical structure
Reference substance name:
Hafnium
EC Number:
231-166-4
EC Name:
Hafnium
Cas Number:
7440-58-6
Molecular formula:
Hf
IUPAC Name:
Hafnium
Test material form:
solid: bulk
Specific details on test material used for the study:
Batch No.: C000344287
Appearance: Dark grey powder

Study design

Contact with:
powdered cellulose
Duration of test (contact time):
3 min

Results and discussion

Test results (Oxidising solids)open allclose all
Key result
Sample tested:
4:1 sample-to-cellulose ratio
Parameter:
mean burning time
Result:
> 180 s
Key result
Sample tested:
1:1 sample-to-cellulose ratio
Parameter:
mean burning time
Result:
> 180 s
Key result
Sample tested:
reference: 3:7 mixture potassium bromate + cellulose
Parameter:
mean burning time
Result:
131 s

Applicant's summary and conclusion

Interpretation of results:
GHS criteria not met
Conclusions:
The burning time of the mixtures of the test item with cellulose (4:1 and 1:1) was greater than the burning time of the reference mixture of potassium bromate and cellulose (3:7).
Due to the tests the test item does not have to be classified as oxidizing solid.
UN Transport Regulation: the test item does not have to be classified as oxidizing solid in Division 5.1 according to the UN Transport Regulation
GHS and EC 1272/2008 (CLP Regulation): the test item does not have to be classified as oxidizing solid according to GHS and EC 1272/2008 (CLP Regulation) Annex 1: 2.14.
Executive summary:

The burning time of the mixtures of the test item with cellulose (4:1 and 1:1) was greater than the burning time of the reference mixture of potassium bromate and cellulose (3:7). Due to the tests the test item does not have to be classified as oxidizing solid.

UN Transport Regulation: the test item does not have to be classified as oxidizing solid in Division 5.1 according to the UN Transport Regulation

GHS and EC 1272/2008 (CLP Regulation): the test item does not have to be classified as oxidizing solid according to GHS and EC 1272/2008 (CLP Regulation) Annex 1: 2.14.