Registration Dossier

Administrative data

First-aid measures

4.1 Description of first aid measures
General advice
:
Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Symptoms of poisoning may appear several hours later.
Do not leave the victim unattended.
If inhaled
:
Call a physician or poison control centre immediately.
Move to fresh air.
If unconscious, place in recovery position and get medical attention immediately.
In case of skin contact
:
If skin irritation persists, call a physician.
Wash contaminated clothing before reuse.
If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact
:
Remove contact lenses.
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed
:
Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms
:
Skin contact may provoke the following symptoms:
Allergic reactions
Redness
Inhalation may provoke the following symptoms:
Shortness of breath
Asthma
Ingestion may provoke the following symptoms:
Stomach/intestinal disorders
Eye contact
Excessive lachrymation
4.3 Indication of any immediate medical attention and special treatment needed

Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media
:
Water mist
Water spray jet
Foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing media
:
High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting
:
Do not allow run-off from fire fighting to enter drains or water courses.
Hazardous combustion prod-ucts
:
Carbon oxides
Metal oxides
Hazardous decomposition products due to incomplete com-bustion
5.3 Advice for firefighters
Special protective equipment for firefighters
:
Wear self-contained breathing apparatus for firefighting if nec-essary.
Further information
:
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored sepa-rately in closed containments.
Use a water spray to cool fully closed containers.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions
:
Use personal protective equipment.
Avoid dust formation.
Avoid breathing dust.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
6.2 Environmental precautions
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
:
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13).
Keep in suitable, closed containers for disposal.
6.4 Reference to other sections

Handling and storage

7.1 Precautions for safe handling
Advice on safe handling
:
Handle under nitrogen, protect from moisture.
Avoid formation of respirable particles.
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-plication area.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national regulations.
Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.
Advice on protection against fire and explosion
:
Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed. Keep away from open flames, hot surfaces and sources of ignition. Keep away from combus-tible material.
Hygiene measures
:
Avoid contact with skin, eyes and clothing. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
:
Prevent unauthorized access. No smoking. Store in cool place. Containers which are opened must be carefully re-sealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. To maintain product quality, do not store in heat or direct sunlight.
Further information on stor-age conditions
:
Store contents under inert gas.
Storage class (TRGS 510)
:
4.2, Pyrophoric and self-heating hazardous materials
Further information on stor-age stability
:
Keep in a dry place. No decomposition if stored and applied as directed.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

8.1 Control parameters
Occupational Exposure Limits Components CAS-No. Value type (Form of exposure) Control parameters Basis
iso-hexane
107-83-5
AGW
500 ppm
1.800 mg/m3
DE TRGS 900
Peak-limit: excur-sion factor (catego-ry)
2;(II)
Further information
Senate commission for the review of compounds at the work place dangerous for the health (MAK-commission).
TWA
500 ppm
ACGIH
STEL
1.000 ppm
ACGIH
Occupational exposure limits of decomposition products Components CAS-No. Value type (Form of exposure) Control parameters Basis
carbon monoxide
630-08-0
AGW
30 ppm
35 mg/m3
DE TRGS 900
Peak-limit: excur-sion factor (catego-ry)
2;(II)
Further information
Senate commission for the review of compounds at the work place dangerous for the health (MAK-commission)., When there is compliance with the OEL
and biological tolerance values, harm to the unborn child can not be excluded
TWA
20 ppm
23 mg/m3
2017/164/EU
Further information
Indicative
STEL
100 ppm
117 mg/m3
2017/164/EU
Further information
Indicative
TWA
25 ppm
ACGIH
8.2 Exposure controls
Engineering measures
Handle only in a place equipped with local exhaust (or other appropriate exhaust).
Personal protective equipment
Eye protection
:
Safety glasses with side-shields conforming to EN166
Hand protection
Material
:
Nitrile rubber
Break through time
:
> 240 min
Glove thickness
:
0,38 mm
Skin and body protection
:
Dust impervious protective suit
Respiratory protection
:
ABEK-P3-filter
Filter type
:
Combined particulates, inorganic and acidic gas/vapour, ammonia/amines and organic vapour type (ABEK-P)
In the case of dust or aerosol formation use respirator with an approved filter.
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Stability and reactivity

10.1 Reactivity
Self-heating: may catch fire.
10.2 Chemical stability
The product will oxidize in air and release heat.
10.3 Possibility of hazardous reactions
Hazardous reactions
:
No decomposition if stored and applied as directed.
Dust may form explosive mixture in air.
10.4 Conditions to avoid
Conditions to avoid
:
Possible emission of gaseous decomposition products may lead to a dangerous pressure build-up.
Take measures to prevent the build up of electrostatic charge.
Heat, flames and sparks.
Exposure to air.
10.5 Incompatible materials
Materials to avoid
:
Strong oxidizing agents
May cause uncontrolled reactions in presence of functional groups.
10.6 Hazardous decomposition products
Hazardous decomposition products
:
Carbon monoxide
Hazardous decomposition products
:
carbon monoxide

Disposal considerations

13.1 Waste treatment methods
Product
:
The product should not be allowed to enter drains, water courses or the soil.
Dispose of in accordance with the European Directives on waste and hazardous waste.
In accordance with local and national regulations.
Do not contaminate ponds, waterways or ditches with chemi-cal or used container.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Send to a licensed waste management company.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.