Registration Dossier

Administrative data

First-aid measures

1 Description of first aid measures
· General information:
Personal protection for the First Aider.
Immediately remove any clothing soiled by the product.
Take affected persons out of danger area and lay down.
Position and transport stably in side position.
Artificial respiration with respiration bag or respirator
· After inhalation:
Take affected persons into fresh air and keep quiet.
Seek medical treatment in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse out mouth and then drink plenty of water.
Vomiting, possible danger of aspiration, keep breathing passages free
Induce vomiting only, if affected person is fully conscious.
Seek medical treatment.

2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Hazards:
Danger of absorption through skin

3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

Fire-fighting measures

1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray.

2 Special hazards arising from the substance or mixture
Nitrogen oxides (NOx)
Hydrogen cyanide (prussic acid)
Carbon monoxide and carbon dioxide
Danger of forming toxic pyrolysis products.

3 Advice for firefighters
· Protective equipment:
Wear fully protective suit.
Do not inhale explosion gases or combustion gases.
Self-contained respiratory protective device.
· Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.

Accidental release measures


1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Keep away from ignition sources.

2 Environmental precautions:
Do not allow to enter sewers/ surface or ground water.

3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to "Disposal considerations".
Ensure adequate ventilation.

Handling and storage

1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.

2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
· Information about storage in one common storage facility:
Do not store together with strong acids, alkalines and oxidation agents
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Store receptacle in a well ventilated area.
Protect from exposure to the light.
Avoid contact with air / oxygen.
· Recommended storage temperature:
At 20 °C to 30 °C

3 Specific end use(s)
No further relevant information available.

Transport information

Land transport (ADR/RID)

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ethoxyquin)
Chemical name:
ethoxyquin
Language:
English
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
9
Special Provisions:
· Limited quantities (LQ): 5L
· Excepted quantities (EQ):
Code: E1
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 1000 mL
· Transport category: 3
· Tunnel restriction code: E
Remarks:
· Special marking: Symbol (fish and tree)

Inland waterway transport (ADN(R))

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ethoxyquin)
Chemical name:
ethoxyquin
Language:
English
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ethoxyquin)
Chemical name:
ethoxyquin
Class:
9 (M6) Miscellaneous dangerous substances and articles.
Packaging group:
III
EmS code:
F-A,S-F
Labels:
9
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ethoxyquin)
Chemical name:
ethoxyquin
Class:
9 (M6) Miscellaneous dangerous substances and articles.
Packaging group:
III
Labels:
9
Remarks
· Special marking: Symbol (fish and tree)

Additional transport information

Additional transport information
· Danger code (Kemler): 90

Exposure controls / personal protection

· Additional information about design of technical facilities: No further data; see "Handling & Storage".
1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
Not required.
· Additional information:
The lists valid during the making were used as basis.

2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Do not inhale gases / fumes / aerosols / dust.
Immediately remove all soiled and contaminated clothing.
Avoid contact with the eyes and skin.
· Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
· Recommended filter device for short term use:
Filter A
· Protection of hands:
Protective gloves
· Material of gloves:
Synthetic rubber gloves
· Penetration time of glove material:
Penetration time ≥ 8 h
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Not suitable are gloves made of the following materials:
Leather gloves
Strong material gloves
· Eye protection:
Safety glasses

Stability and reactivity

1 Reactivity
No further relevant information available.

2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Discoloures in air-and light.

3 Possibility of hazardous reactions
Reacts with strong acids, alkalines and oxidizing agents.

4 Conditions to avoid
No further relevant information available.

5 Incompatible materials
No further relevant information available.

6 Hazardous decomposition products
Nitrogen oxides (NOx)
Hydrogen cyanide (prussic acid)
Carbon monoxide and carbon dioxide
Danger of forming toxic pyrolysis products.

Disposal considerations

1 Waste treatment methods
· Recommendation :
Disposal considering to the local / regional / national / international regulations. Details have to be arranged with the authority concerned and / or the local waste management enterprise.
· Waste disposal key:
Depending on the application intended by the consumer, the allocation of waste codes according to the European waste catalogue has to be carried out in agreement with the waste disposal company and the authority.

· Uncleaned packaging:
· Recommendation:
Packaging may be reused or recycled after cleaning.
Packagings that may not be cleansed are to be disposed of in the same manner as the product.
· Recommended cleansing agents:
Water, if necessary together with cleansing agents.