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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: well performed study according to accepted standard

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2015
Report date:
2015

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.17 (Oxidising Properties (Solids))
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
N-(4-chlorophenyl)-2-[(4-methyl-2-nitrophenyl)azo]-3-oxobutyramide
EC Number:
260-618-3
EC Name:
N-(4-chlorophenyl)-2-[(4-methyl-2-nitrophenyl)azo]-3-oxobutyramide
Cas Number:
57206-89-0
Molecular formula:
C17H15ClN4O4
IUPAC Name:
N-(4-chlorophenyl)-2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxobutanamide

Study design

Contact with:
other: Barium nitrate

Results and discussion

Test results (Oxidising solids)open allclose all
Sample tested:
reference mixture (not specified)
Remarks:
migrated information
Parameter:
maximum burning rate
Result:
1.61 other: mm/s (migrated information)
Remarks on result:
other: Barium nitrate : Cellulose = 60 : 40 under air.
Sample tested:
test mixture (not specified)
Remarks:
migrated information
Parameter:
maximum burning rate
Result:
1.65 other: mm/s (migrated information)
Remarks on result:
other: Cellulose : Test item = 50 : 50 under air
Sample tested:
test mixture (not specified)
Remarks:
migrated information
Parameter:
maximum burning rate
Result:
other: no propargation
Remarks on result:
other: Kieselguhr : Test item = 50 : 50 under air. The mixture etinguished after 2 seconds
Sample tested:
reference mixture (not specified)
Remarks:
migrated information
Parameter:
maximum burning rate
Result:
0.99 other: mm/s (migrated information)
Remarks on result:
other: Barium nitrate : Cellulose = 60 : 40 under argon.
Sample tested:
test mixture (not specified)
Remarks:
migrated information
Parameter:
maximum burning rate
Result:
other: the mixture could not be ignited
Remarks on result:
other: Cellulose : Test item = 50 : 50 under argon

Applicant's summary and conclusion

Interpretation of results:
other: no oxidising properties
Remarks:
Migrated information
Conclusions:
The test item had no oxidizing properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A.17.
Executive summary:

The substance was tested for oxidizing properties according to European Commission Regulation (EC) No. 440/2008, A.17. Oxidizing properties of solids.

Four tests were performed for the reference mixture (barium nitrate and cellulose) with 50, 55, 60 and 70 wt. % oxidizer (barium nitrate). The highest burning rate of 1.61 mm/s was found for the mixture with 60 wt. % oxidizer.

Mixtures of the test item with cellulose were prepared in between 10 and 70 wt. % of the test item and were tested.

The maximum burning rate of the mixtures of the test item and cellulose (1.65 mm/s) was higher than the maximum burning rate of the reference mixture of cellulose and barium nitrate (1.61 mm/s) . Therefore the additional tests with kieselguhr and under an inert atmosphere had to be performed.

The mixture of test item (50 %) with Kieselgur showed no propagating combustion. Due to this result a further test under inert atmosphere was necessary.

A mixture of the test item with cellulose was prepared using 50 % of the test item. A mixture of barium nitrate with cellulose was prepared using 60 wt.% of barium nitrate. The mixtures were tested under argon atmosphere.

The mixture of cellulose and test item could not be ignited, only decomposition was oberserved. The mixture of barium nitrate and cellulose showed a burning rate of 0.99 mm/s.

Due to the results of the experiments in an inert atmosphere, it can be stated that the test item had no oxidizing properties.