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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

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Administrative data

Endpoint:
pyrophoric solids
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
test procedure in accordance with national standard methods with acceptable restrictions
Remarks:
no GLP

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2016
Report date:
2016

Materials and methods

Test guideline
Qualifier:
no guideline followed
Principles of method if other than guideline:
Reaction of the test substance in contact with air is tested (spontaneous ignition - yes or no). Test method is applicable for liquids and solids. Test method is not applicable for substances, that have to be exposed to air for hours or days or at higher temperatures, before they ignite.
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Octacarbonyldicobalt
EC Number:
233-514-0
EC Name:
Octacarbonyldicobalt
Cas Number:
10210-68-1
Molecular formula:
C8O8Co2
IUPAC Name:
1,1,1,3,3,3-hexakis(oxidaniumylidynemethyl)-2,4-dioxo-1,3-dicobaltabicyclo[1.1.0]butane-1,1,3,3-tetrakis(ylium)
Test material form:
solid: particulate/powder
Remarks:
crystalline powder

Results and discussion

Pyrophoric solids
Key result
Remarks on result:
other: substance is not pyrophoric

Applicant's summary and conclusion

Conclusions:
The study was performed comparable to guideline study with acceptable restrictions and therefore reliability of Klimisch 2 has been assigned. No ignition has been observed in six separate testings and hence, the result is negative (not pyrophoric).
Executive summary:

Reaction of the test substance in contact with air is tested (spontaneous ignition - yes or no). For the test, 1 to 2 cm3 of the powdery substance to be tested is poured from circa 1 m height onto a non-combustible surface and it is observed whether the substance ignites during dropping or within five minutes of settling. The test is performed six times unless ignition occurs.

No ignition has been observed in six separate testings and hence, the result is negative (substance is not pyrophoric).

Only a slow colour change of the test substance from orange-brown to dark brown has been observed. Further, one filling emitted smoke.