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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Version / remarks:
Council Regulation (EC) No 440/2008 A. 16
Deviations:
no
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
6-amino-4-hydroxynaphthalene-2-sulphonic acid
EC Number:
202-000-8
EC Name:
6-amino-4-hydroxynaphthalene-2-sulphonic acid
Cas Number:
90-51-7
Molecular formula:
C10H9NO4S
IUPAC Name:
6-amino-4-hydroxynaphthalene-2-sulphonic acid
Test material form:
solid: particulate/powder

Results and discussion

Relative self-ignition temperature (solids)
Key result
Relative self-ignition temperature:
278 °C

Applicant's summary and conclusion

Conclusions:
The GLP study was performed according to EU method A.16 without deviations and therefore reliability of Klimisch 1 has been assigned. The auto ignition temperature has been determined at 278 °C.
Executive summary:

The auto ignition temperature of the test substance was determined in a GLP test according to EU method A.16. The substance under test was placed in a wire basket with 8 mL volume in an oven at room temperature. The oven was heated up with a rate of 0.5 K/min up to 420 °C. The temperature of the center of the sample and the temperature of an inert reference sample, which was placed in the oven too, were recorded. For the purpose of this test, the temperature of the

oven at which the sample temperature reached 400 °C by self-heating is called the selfignition temperature.

In the temperature/time plot is a weak endothermic peak in the range from about 130 °C to 170 °C (oven temperature). In the range from 270 °C to 270 °C (oven temperature) is a strong exothermic peak with a temperature maximum of the substance from 496 °C. The sample temperature from 400 °C is reached at an oven temperature from 278 °C, which is the auto-ignition temperature.