Di-mu-chloro-bis(hapto-1,5-cyclooctadiene)dirhodium(I)

Guidance on Safe Use

First-aid measures

Description of first aid measures
· General information: In case of accident or if you feel unwell, seek medical advice immediately.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Immediately remove all soiled and contaminated clothing
If skin irritation continues, consult a doctor.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse out mouth and then drink plenty of water.
Seek immediate medical advice.
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

Fire-fighting measures

· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Hydrocarbons
· Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
· Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Prevent any seepage into the ground.

Accidental release measures

·Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Avoid formation of dust.
Ensure adequate ventilation
· Environmental precautions:
Do not allow to penetrate the ground/soil.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Pick up mechanically.
Send for recovery or disposal in suitable receptacles.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

Handling and storage

Precautions for safe handling
Wear protective equipment. Keep unprotected persons away.
Prevent formation of dust.
Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection:
Product is not flammable.
see chapter 5
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in dry conditions.
Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Specific end use(s) No further relevant information available.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

Void

Shipping

Labels:

Void

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

Void

Shipping information

Proper shipping name and description:

Void

Labels:

Void

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

Void

Shipping information

Proper shipping name and description:

Void

Labels:

Void

Remarks

SpecialProvisions

Exposure controls / personal protection

· Additional information about design of technical facilities:
Ensure good ventilation/exhaustion at the workplace.
No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Do not eat or drink while working.
Avoid contact with the eyes and skin.
Wash hands before breaks and at the end of work.
· Respiratory protection:
Use respiratory protective device against the effects of fumes/dust/aerosol.
Filter P3
· Protection of hands: Protective gloves
· For the permanent contact of a maximum of 15 minutes gloves made of the following materials are
suitable:
Nitrile rubber, NBR
Fluorocarbon rubber (Viton)
· Eye protection: Tightly sealed goggles
· Body protection: Protective work clothing

Stability and reactivity

- Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: Hydrocarbons
· Additional information:

Disposal considerations

Waste treatment methods
· Recommendation
Contact manufacturer for recycling information.
Disposal must be made according to official regulations.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.