Registration Dossier
Registration Dossier
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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 604-481-3 | CAS number: 14559-13-8
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Inhalation
Remove from exposure to fresh air. Obtain medical attention.
Skin contact
Take off all contaminated clothing immediately. Wash off immediately with soap and plenty of water. Consult a physician.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Cunsult a physician.
Ingestion
Drink plenty of water. Obtain medical attention.
Most important symptoms and effects, both acute and delayed
May cause sensitization by skin contact.
Indication of immediate medical attention and special treatment needed
Treatment according to symptoms.
Fire-fighting measures
Suitable extinguishing media
Water spray, foam, dry chemical, carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture
Hazardous decomposition products: SOx, COx.
Advice for firefighters
Wear self-contained breathing apparatus and protective suit.
Other information
Cool containers with water spray.
Accidental release measures
Evacuate personnel to safe areas. Remove all sources of ignition. Avoid contact with the skin. Use personal protective equipment.
Environmental precautions
Should not be released into the aquatic environment or drains.
Methods and materials for containment and cleaning up
Adsorption in inert material (e.g. sand or universal binder). Take up mechanically and collect in suitable container for disposal. Dispose of as special waste in compliance with local and national regulations.
Reference to other sections
Information regarding personal protective equipment, see section "Exposure controls/personal protection". Information regarding waste disposal, see Section "Disposal considerations".
Handling and storage
Precautions for safe handling
Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or ehhaust in work rooms. Do not breathe gas/fumes/vapour/spray. Use personal protective equipment. Provide work rooms with safety shower and eye wash bottle with pure water. Have a shower after handling the product.
Conditions for safe storage, including any incompatibilities
Keep containers tightly closed in a cool, well-ventilated place. Keep at temperatures above 0°C. Protect from light. Keep container dry. Keep away from heat and sources of ignition.
Specific end use(s)
No data.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3082
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- -
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Marine transport (UN RTDG/IMDG)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, liquid, n.o.s. (Protiothiophene)
- Chemical name:
- Methyl 4,5-dimethyl-3-thiophenecarboxylate
- Labels:
- 90
- Marine pollutant
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, liquid n.o.s. (Protiothiophene)
- Chemical name:
- Methyl 4,5-dimethyl-3-thiophenecarboxylate
- Labels:
- 90
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Exposure controls / personal protection
Control parameters
Other information on limit values
No information available.
Limit values on other countries
No data available.
DNELS
Not known
PNECS
Not known
Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Do not breathe vapours. Have a wash after handling the product. Take off all contaminated clothing immediately. Wash contaminated clothing before re-use.
Individual protection measures
Respiratory protection
Respirator with A/P2-filter. ABEK-P3 is applicable. Fresh air blower if needed.
Hand protection
Chemical-resistant gloves; For example Butyl-gloves. Break through times: no data available.
Eye/face protection
Safety goggles / face-shield.
Skin protection
Protective suit.
Environmental exposure controls
Should not be released into the environment.
Stability and reactivity
No spesific reactivity known when stored and handled according to prescribed instructions.
Chemical stability
No data available.
Possibility of hazardous reactions
Not if used and storage under normal recommended conditions.
Conditions to avoid
Keep away from heat and sources of ignition.
Incompatible materials
Strong oxidizing agents. Hydrolyzes with alkali hydroxides.
Hazardous decomposition products
Carbon oxides, sulfur oxides (COx, SOx).
Disposal considerations
Dispose of as special waste in compliance with local and national regulations.
Waste from residues/unused products
Dispose of residues and contaminated packaging as a special waste in compliance with local and national regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.