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Diss Factsheets

Physical & Chemical properties

Explosiveness

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Link to relevant study record(s)

Description of key information

Lithium bis(oxalato)borate is not explosive as organo-lithium compounds are unlikely to have explosive properties and the calculated oxygen balance is less than -200. Moreover, when tested for dust explosiveness according to VDI 2263 (Dust fires and dust explosions; hazards, assessment, protective measures) lithium bis(oxalato)borate did not ignite and did not reveal dust explosiveness under test conditions. Further lithium bis(oxalato)borate does not present a danger of explosion under the test conditions observed in a study according to EU method A.13.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

When tested for dust explosiveness according to VDI 2263 (Dust fires and dust explosions; hazards, assessment, protective measures) lithium bis(oxalato)borate did not ignite and did not reveal dust explosiveness under test conditions. (Siemens, 2008)

In a second study report the explosive properties of lithium bis(oxalato)borate were assessed according to EU method A.14. The test item was tested in two mechanical sensitivity tests (shock and friction), as well as the thermal sensitivity test under the influence of a flame. The sample did not show a danger of explosiveness under the named test conditions. (SRICI, 2010)

Justification for classification or non-classification

Based on these results of the experimental test and theoretical evaluations, lithium bis(oxalato)borate is not to be classified and labelled according to Directive 67/548/EEC (DSD) and Regulation (EC) No 1272/2008 (CLP).