Registration Dossier
Registration Dossier
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EC number: 231-084-9 | CAS number: 7435-12-3
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures:
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim
warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Inhalation is possible if aerosols, mists, dusts, or smoke form.
Move victims into fresh air.
With labored breathing: Provide with oxygen. Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
In case of persistent discomfort: Consult an ophthalmologist.
Ingestion:
Rinse mouth.
Immediately give large quantities of water to drink.
Obtain medical attention.
Most important symptoms and effects, both acute and delayed:
Symptoms:
None known
Hazards:
Other dangerous properties can not be excluded.
Indication of any immediate medical attention and special treatment needed:
This substance has no remarkable acute health hazard potential. Acute health damage is therefore not to be expected.
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim
warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Inhalation is possible if aerosols, mists, dusts, or smoke form.
Move victims into fresh air.
With labored breathing: Provide with oxygen. Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
In case of persistent discomfort: Consult an ophthalmologist.
Ingestion:
Rinse mouth.
Immediately give large quantities of water to drink.
Obtain medical attention.
Most important symptoms and effects, both acute and delayed:
Symptoms:
None known
Hazards:
Other dangerous properties can not be excluded.
Indication of any immediate medical attention and special treatment needed:
This substance has no remarkable acute health hazard potential. Acute health damage is therefore not to be expected.
Fire-fighting measures
Extinguishing media:
Suitable extinguishing media: Water spray jet
Foam
Carbon dioxide (CO2)
Dry powder
Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
Hazard-determining flue gases might develop in case of fire:
hydrogen chloride
nitrogen oxides (NOx)
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
In case of fire, remove the endangered barrels and bring to a safe place, if this can be done safely.
Keep out unprotected persons.
Wear a self contained respiratory apparatus
Suitable extinguishing media: Water spray jet
Foam
Carbon dioxide (CO2)
Dry powder
Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
Hazard-determining flue gases might develop in case of fire:
hydrogen chloride
nitrogen oxides (NOx)
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
In case of fire, remove the endangered barrels and bring to a safe place, if this can be done safely.
Keep out unprotected persons.
Wear a self contained respiratory apparatus
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear personal protective equipment; see "Exposure controls/personal protection".
Avoid formation of dust. Ensure sufficient ventilation.
Environmental precautions:
Observe regulations on prevention of water pollution (check, dam up, cover up).
Do not allow entrance in sewage water, soil, stretches of water, drainage systems, surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Collect up material. Transfer into suitable containers for recovery or disposal.
Disposal according to local authority regulations.
Avoid dust formation.
Reference to other sections:
Wear personal protective equipment; see "Exposure controls/personal protection".
Wear personal protective equipment; see "Exposure controls/personal protection".
Avoid formation of dust. Ensure sufficient ventilation.
Environmental precautions:
Observe regulations on prevention of water pollution (check, dam up, cover up).
Do not allow entrance in sewage water, soil, stretches of water, drainage systems, surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Collect up material. Transfer into suitable containers for recovery or disposal.
Disposal according to local authority regulations.
Avoid dust formation.
Reference to other sections:
Wear personal protective equipment; see "Exposure controls/personal protection".
Handling and storage
Precautions for safe handling:
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Ensure that apparatus and pipelines are free from leaks. Do not ventilate into the open.
Dedicated loading/unloading stations required.
Trained personnel must be used.
Conditions for safe storage, including any incompatibilities:
Advice on protection against fire and explosion:
Keep away from combustion sources such as sparks, flames and unprotected light sources.
When using do not smoke.
Take precautionary measures against static charges, keep away from sources of ignition.
Storage:
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
Further information:
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.
German storage class:
11 - Combustible Solids
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Ensure that apparatus and pipelines are free from leaks. Do not ventilate into the open.
Dedicated loading/unloading stations required.
Trained personnel must be used.
Conditions for safe storage, including any incompatibilities:
Advice on protection against fire and explosion:
Keep away from combustion sources such as sparks, flames and unprotected light sources.
When using do not smoke.
Take precautionary measures against static charges, keep away from sources of ignition.
Storage:
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
Further information:
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.
German storage class:
11 - Combustible Solids
Transport information
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Marine transport (UN RTDG/IMDG)
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Additional transport information
Additional information
- Special provisions / remarks / other:
- Transport prohibited
Exposure controls / personal protection
Control parameters:
Other information:
Contains no substances with occupational exposure limit values.
DNEL/DMEL values:
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.
PNEC values:
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.
Exposure controls:
Engineering measures:
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Do not lead exhaust air back to workplace areas unfiltered.
Exhaust filter or scrubber.
Exhaust air filter (HEPA-filter)
Do not add wastewater to a biological wastewater treatment plant
All precautionary measures indicated have to be observed.
Provide for installation of emergency shower and eye bath.
Exposure controls:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.
Personal protective equipment:
Respiratory protection:
If dust occurs: Respirator with P3 particle filter
Accidental release measures:
In the case of respirable dust, use self-contained breathing apparatus.
Note time limit for wearing respiratory protective equipment.
Hand protection:
Glove material Nitrile, for example, Dermatril 740, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.11 mm
Method: DIN EN 374
Accidental release measures:
Glove material Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.65 mm
Method: DIN EN 374
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by
analogy with similar materials.
Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined
according to EN 374 due to the many different influential factors involved (e.g. temperature).
Eye protection:
Safety glasses with side-shields conforming to EN166
Accidental release measures:
close-fitting protective goggles (e.g. closed goggles)
Skin and body protection:
suitable protective clothing - Use disposable clothing if appropriate.
Hygiene measures:
Do not eat, drink, smoke, or sniff while at work. Wash your hands and/or face before breaks and before termination of work.
Take off clothing and shoes contaminated with product. Clean before reuse.
Preventive skin protection is recommended.
Use barrier cream regularly.
Cleanse and apply cream to skin after work.
Protective measures:
All precautionary measures indicated have to be observed.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Regular safety training is a must.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
Environmental exposure controls:
In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease
emissions to acceptable values.
Other information:
Contains no substances with occupational exposure limit values.
DNEL/DMEL values:
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.
PNEC values:
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.
Exposure controls:
Engineering measures:
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Do not lead exhaust air back to workplace areas unfiltered.
Exhaust filter or scrubber.
Exhaust air filter (HEPA-filter)
Do not add wastewater to a biological wastewater treatment plant
All precautionary measures indicated have to be observed.
Provide for installation of emergency shower and eye bath.
Exposure controls:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.
Personal protective equipment:
Respiratory protection:
If dust occurs: Respirator with P3 particle filter
Accidental release measures:
In the case of respirable dust, use self-contained breathing apparatus.
Note time limit for wearing respiratory protective equipment.
Hand protection:
Glove material Nitrile, for example, Dermatril 740, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.11 mm
Method: DIN EN 374
Accidental release measures:
Glove material Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.65 mm
Method: DIN EN 374
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by
analogy with similar materials.
Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined
according to EN 374 due to the many different influential factors involved (e.g. temperature).
Eye protection:
Safety glasses with side-shields conforming to EN166
Accidental release measures:
close-fitting protective goggles (e.g. closed goggles)
Skin and body protection:
suitable protective clothing - Use disposable clothing if appropriate.
Hygiene measures:
Do not eat, drink, smoke, or sniff while at work. Wash your hands and/or face before breaks and before termination of work.
Take off clothing and shoes contaminated with product. Clean before reuse.
Preventive skin protection is recommended.
Use barrier cream regularly.
Cleanse and apply cream to skin after work.
Protective measures:
All precautionary measures indicated have to be observed.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Regular safety training is a must.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
Environmental exposure controls:
In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease
emissions to acceptable values.
Stability and reactivity
Reactivity:
No further information available
Chemical stability:
No further information available
Possibility of hazardous reactions:
Possibility of hazardous reactions: No special measures are required.
Conditions to avoid:
No further information available
Incompatible materials:
No further information available
Hazardous decomposition products:
No hazardous decomposition products known.
No further information available
Chemical stability:
No further information available
Possibility of hazardous reactions:
Possibility of hazardous reactions: No special measures are required.
Conditions to avoid:
No further information available
Incompatible materials:
No further information available
Hazardous decomposition products:
No hazardous decomposition products known.
Disposal considerations
Waste treatment methods:
Product:
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Do not add wastewater to a biological wastewater treatment plant.
Bring used exhaust air filter for incineration.
Disposal according to local authority regulations.
Uncleaned packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Waste Key Number:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Product:
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Do not add wastewater to a biological wastewater treatment plant.
Bring used exhaust air filter for incineration.
Disposal according to local authority regulations.
Uncleaned packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Waste Key Number:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
