Benzenamine, reaction products with aniline hydrochloride and nitrobenzene

Auto flammability

Link to relevant study record(s)

Reference

Reference 1

Endpoint:

relative self-ignition temperature (solids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

15 November 2006 to 4 December 2006

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

other: Study conducted to GLP in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results.

Qualifier:

according to guideline

Guideline:

EU Method A.16 (Relative Self-Ignition Temperature for Solids)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Relative self-ignition temperature:

ca. 252 °C

Remarks on result:

other: No measures of pressure were recorded or provided in study

Observations after the test:

The cube contained a small amount of black/orange charred remains.

Conclusions:

The test material has been determined to have a relative self-ignition temperature of 252 °C.

Executive summary:

In a hazardous physico-chemical properties study (0370/0352), the relative self-ignition temperature of the test material was determined to be 252 °C, according to EU Test Method A16.

Reference 2

Endpoint:

auto-flammability

Type of information:

experimental study

Adequacy of study:

supporting study

Study period:

22 December 2010

Reliability:

4 (not assignable)

Rationale for reliability incl. deficiencies:

other: Study conducted in accordance with generally accepted scientific principles, with incomplete reporting or methodological deficiencies. There is not enough information contained within the summary report to accurately assign reliability.

Qualifier:

according to guideline

Guideline:

other: “Recommendations on the TRANSPORT OF DANGEROUS GOODS - Manual of Tests and Criteria - Third revised edition”.

Deviations:

no

GLP compliance:

not specified

In the first part of the test, the following results were obtained:

Sample	Result
1	No ignition
2	No ignition
3	No ignition
4	No ignition
5	No ignition
6	No ignition

 

In the second part of the test, the following results were obtained:

Temperature  (°C)	Container Size  (mm)	Sample Amount (g)	Result
140	100	398.3	Heating 60°C greater than the oven temperature was observed
140	25	5.3	Heating 60°C greater than the oven temperature was not observed
120	100	371.2	Heating 60°C greater than the oven temperature was observed
100	100	389.0	Heating 60°C greater than the oven temperature was not observed

Conclusions:

Under the conditions of the study, no self-ignition of the test substance was seen in air.

Executive summary:

A study was conducted that combined two individual tests, Ignition in Air and Self-heating Properties, in accordance with Methods outlined in the “Recommendations on the TRANSPORT OF DANGEROUS GOODS - Manual of Tests and Criteria - Third revised edition”. Under the conditions of the study, no self-ignition of the test substance was seen in air.

Description of key information

The test material has been determined to have a relative self-ignition temperature of 252 °C.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:

252 °C

Additional information

In a hazardous physico-chemical properties study (0370/0352), the relative self-ignition temperature of the test material was determined to be 252 °C, according to EU Test Method A16. The study was awarded a reliability score of 1 in accordance with the criteria set forth by Klimisch et al. (1997). The relative self-ignition temperature of the test material was determined to be 252 °C.

In addition, a study was conducted that combined two individual tests, Ignition in Air and Self-heating Properties, in accordance with Methods N2 and N4 of the “Recommendations on the TRANSPORT OF DANGEROUS GOODS - Manual of Tests and Criteria - Third revised edition”. The study was awarded a reliability score of 4 in accordance with the criteria set forth by Klimisch et al. (1997). Under the conditions of the study, no self-ignition of the test substance was seen in air.