Registration Dossier
Registration Dossier
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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 682-678-3 | CAS number: 182121-12-6
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
· Description of first aid measures
· General information: Take note of the following instructions:
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in the recovery position for transportation.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Fire-fighting measures
· Extinguishing media
· For safety reasons unsuitable extinguishing agents: No further relevant information available.
· Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
· Advice for firefighters
· Protective equipment: Do not inhale explosion gases or combustion gases.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Accidental release measures
· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up: Pick up mechanically.
Handling and storage
· Precautions for safe handling
Store in cool, dry place in tightly closed receptacles.
Prevent static electric sparks.
Avoid formation of respirable particles.
Any unavoidable deposit of dust must be regularly removed.
Use appropriate industrial vacuum cleaners or central vacuum systems for dust removal.
· Information about fire - and explosion protection:
The product is flammable.
Product dust together with air may develop ignitable and explosive mixtures.
Earth container to avoid electric sparks, especially in contact with flammable substances.
Air turbulences of product dust particles will cause an explosive atmosphere.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Use only receptacles specifically permitted for this substance/product.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: None.
· Specific end use(s) Not applicable.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (9,9-bis(4-hydroxyphenyl)fluorene)
- Labels:
- 9
Special provisions / remarks
- Special provisions:
- · Special marking: Symbol (fish and tree)
- Remarks:
- · Limited quantities (LQ): 5 kg
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 1000 g
· Transport category: 3
· Tunnel restriction code: E
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3077
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (9,9-bis(4-hydroxyphenyl)fluorene)
- Labels:
- 9
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (9,9-bis(4-hydroxyphenyl)fluorene)
- Labels:
- 9
Special provisions / remarks
- Remarks:
- · Special marking: Symbol (fish and tree)
UN No. 3077
Special provisions: A97, A158, A179, A197
Danger Code: 9L
UN packing group: III
PASSENGER AND CARGO AIRCRAFT:
Excepted Quantities: E1
Packing instruction: 956
max. net quantity per package: 400 kg
Limited Quantity:
Packing instruction: Y956
max. net quantity per package: 30 kg G
CARGO AIRCRAFT:
Packing instruction: 956
max. net quantity per package: 400 kg
GRACE recommends CARGO AIRCRAFT only.
Additional transport information
Additional information
- Special provisions / remarks / other:
- · Special precautions for user Not applicable.
Warning: Miscellaneous dangerous substances and articles.
· Danger code (Kemler): 90
· EMS Number: F-A,S-F
· Stowage Category: A
· Stowage Code: SW23
· Transport in bulk according to Annex II of Marpol and the IBC Code: Not applicable.
Exposure controls / personal protection
· Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: Valid lists at time of creation were used as basis.
· Exposure controls
· Appropriate engineering controls No further relevant information available.
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
If the WEL value is exceeded.
Filter P2
· Protection of hands:
Protective gloves.
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Preventive skin protection by use of skin-protecting agents is recommended.
· Material of gloves
EN 388: Minimum requirements for efficiency level 1 for all groups.
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Recommended thickness of the material: >= 0.35 mm
· Penetration time of glove material
The exact break through time has to be obtained from the manufacturer of the protective gloves and has to be observed.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes (Permeation according to EN 374 Part 3: Level 6).
EN 420: Minimum requirements for efficiency level 1 for all groups.
· For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
· Not suitable are gloves made of the following materials:
cloth gloves
Leather gloves
· Eye protection:
Tightly sealed goggles
Stability and reactivity
· Reactivity: No further relevant information available.
· Chemical stability: To avoid thermal decomposition do not overheat.
· Possibility of hazardous reactions: Contact with water will cause spontaneous hydrolysis.
· Conditions to avoid
In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes may be developed.
· Incompatible materials: Protect from contamination.
· Hazardous decomposition products: Carbon monoxide and carbon dioxide
Disposal considerations
· Waste treatment methods
· Recommendation:
Disposal must be made according to official regulations.
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.