Registration Dossier
Registration Dossier
Data platform availability banner - registered substances factsheets
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: - | CAS number: -
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Inhalation: Supply fresh air and call for doctor.
Skin contact: Wash skin thoroughly with soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing before use.
Eye contact: Rinse immediately with soft water for at least 15 minutes. Hold eyelids open and remove possible contacts. Seek medical help and continue rinsing during transport.
Ingestion: Rinse mouth with water. Drink a few glasses of water or milk. Never give anything by mouth to an unconscious person. Do not induce vomitng. Consult a physician.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Burning and irritation of the eyes, skin and respiratory tract.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
Treat symptoms and injuries systematically.
Fire-fighting measures
Suitable extinguishing media: Powder
Unsitable Extinguishing Media: Water or foam if there is a risk of contact with the product.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
Heated product or contact with water may cause strong reaction and emit toxic and corrosive fumes. Titanium tetrachloride decomposes in water to titanium dioxide and hydrochloric acid.
ADVICE FOR FIREFIGHTERS
Cool exposed containers with water spray if there is no risk of contact with product. Move container if this can be done safely. Prevent extinguishing media to reach drains or waterways since this could be contaminated. Use self-sustained breathing mask. Protective suit.
Accidental release measures
Alarm and evacuate. Avoid direct contact with product. Provide sufficient ventilation. Use personal protective equipment. Remove all ignition sources.
ENVIRONMENTAL PRECAUTIONS
Avoid release to the environment, sewers or water ways.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
Use explosion-proof equipment and spark-free tools. Sweep or vacuum spilled material. Avoid dust formation. Cover any drains. Place in a suitable container that is tightly closed and marked and dispose as waste.
Handling and storage
Apply occupational hygiene principles and avoid direct contact with product. Do not eat, drink or smoke when handling chemicals. Provide sufficient ventilation. Avoid formation of dust. Use explosion-proof equipment and spark-free tools.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Store as flammable product. Store in original containers, tightly closed in a cool and dry place. Protect from heat and direct sunlight. Ground/bond cointainer and receiving equipment. Avoid contact with air/oxygen. Take precautions against electrostatic build-up. Keep separated from incompatible material and substances.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3396
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, SOLID, WATER- REACTIVE, FLAMMABLE (metal alcoholate, n-heptane)
- Language:
- English
- Labels:
- 4.3+4.1
Special provisions / remarks
- Special provisions:
- 274
- Remarks:
- ADR: Tunnel restriction code: (D/E)
Packing Instruction P410
IBC Instruction IBC04
Tank Instruction T3
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3396
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, SOLID, WATER- REACTIVE, FLAMMABLE (metal alcoholate, n-heptane)
- Labels:
- 4.3+4.1
- Marine pollutant
Special provisions / remarks
- Remarks:
- Special provisions: 274
Packing Instruction P410
IBC Instruction IBC04
Tank Instruction T3
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3396
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, SOLID, WATER- REACTIVE, FLAMMABLE (metal alcoholate, n-heptane)
- Labels:
- 4.3+4.1
Special provisions / remarks
- Remarks:
- Special provisions: A3, A803 (IATA-DGR)
Passenger and Cargo Aircraft:
Packing Instruction P483
Max Net QTY/Pkg 15kg
Cargo Aircraft Only:
Packing Instruction P489
Max Net QTY/Pkg 50kg
Additional transport information
Additional information
- Special provisions / remarks / other:
- Transport in bulk according to Annex II of Marpol and the IBC code: Not applicable
Exposure controls / personal protection
Eye/face protection: Tightly fitted safety goggles
Skin protection: Protective clothing if necessary. Protective gloves shall be used. Suitable material may be Nitrile- or Viton rubber based on components in the substance. Penetration 480 min (EN 374). For more information of suitable material, contact supplier of protective equipment.
Respiratory protection: Respiratory protection shall be used at insufficient ventilation. Filter for dust (particles), (type P3, EN143) and organic vapor with a boiling point >65⁰C, (type A2, EN14389).
Stability and reactivity
Titanium tetrachloride: May react violently with water.
POSSIBILITY OF HAZARDOUS REACTIONS
Titanium tetrachloride: May attack metals in the presence of water or moisture and emit flammable hydrogen gas causing risk of fire and explosion.
CHEMICAL STABILITY
Stable if used and stored as recommended.
CONDITIOINS TO AVOID
Heat, sunlight, ignition sources, moisture.
INCOMPATIBLE MATERIALS
Water, strong oxidizers, alcohols.
HAZARDOUS DECOMPOSITION PRODUCTS
Carbon dioxides. Titanium tetrachloride: Corrosive hydrochloric acid is formed upon contact with water, water vapour or alcohols.
Disposal considerations
Discarded product, including packaging, is considered hazardous waste according to directive 2008/98/EC. Dispose of contents/container to an approved waste disposal plant in accordance with applicable regional, national, and local laws and regulations. Local regulations may be more strict than regional or national requirements and must be complied with.
Empty, well cleaned containers can be recycled.
Waste code shall be selected with regards to the source generating the waste according to valid Waste Regulation.
Example of waste codes/waste designations in accordance with EWC:
Waste type (waste product): EWC 160303* inorganic wastes containing dangerous substances
Waste (packaging): EWC 150110* packaging containing residues of or contaminated by dangerous substances.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.