Ethanone, 1-(1-chlorocyclopropyl)-

Guidance on Safe Use

First-aid measures

General advice
Move out of dangerous area. Place and transport victim in stable position (lying sideways). Remove contaminated clothing immediately and dispose of safely.
Inhalation
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.
Skin contact
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.

 

Fire-fighting measures

Extinguishing media
Suitable
Water spray, Carbon dioxide (CO2), Foam, Sand
Unsuitable
High volume water jet

Special hazards arising from the substance or mixture
In the event of fire the following may be released:, Hydrogen chloride (HCl), Carbon monoxide (CO)

Advice for firefighters
Special protective equipment for firefighters
In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit.
Further information
Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Precautions
Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment. Remove all sources of ignition.

Environmental precautions
Do not allow to get into surface water, drains and ground water.

Methods and materials for containment and cleaning up
Methods for cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal. Decontaminate tools and equipment following cleanup. No sparking tools should be used.

Handling and storage

Precautions for safe handling
Advice on safe handling
The substance is only manufactured and used under strictly controlled conditions in that it is rigorously contained by technical means during its whole lifecycle. Control and procedural technologies shall be used to minimise emission and any resulting exposure.

Advice on protection against fire and explosion
Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge.

Hygiene measures
Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands immediately after work, if necessary take a shower. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).

Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only. Keep away from direct sunlight.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

1993

Shipping information

Proper shipping name and description:

FLAMMABLE LIQUID, N.O.S.
(1-CHLOROCYCLOPROPYL-METHYLKETONE)

Chemical name:

1-(1chlorocyclopropyl)ethanone

Language:

English

Packing group:

Packing group III: Substances presenting low danger

Labels:

Packaging 3
Bulk 3
Haz ID30

Special provisions / remarks

Remarks:

Tunnel Code: D/E

Inland waterway transport (UN RTDG/ADN(R))

UN number:

1993

Shipping information

Proper shipping name and description:

FLAMMABLE LIQUID, N.O.S. (1-CHLOROCYCLOPROPYL-METHYLKETONE)

Chemical name:

1-(1chlorocyclopropyl)ethanone

Language:

English

Packing group:

Packing group III: Substances presenting low danger

Labels:

Packaging 3
Bulk 3
Haz ID30

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

1993

Shipping information

Proper shipping name and description:

FLAMMABLE LIQUID, N.O.S.
(1-CHLOROCYCLOPROPYL-METHYLKETONE)

Chemical name:

1-(1chlorocyclopropyl)ethanone

Language:

English

Packing group:

Packing group III: Substances presenting low danger

EmS code:

F-E

S-E

Labels:

Packaging 3
Bulk 3

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

1993

Shipping information

Proper shipping name and description:

FLAMMABLE LIQUID, N.O.S.
(1-CHLOROCYCLOPROPYL-METHYLKETONE )

Chemical name:

1-(1chlorocyclopropyl)ethanone

Language:

English

Packing group:

Packing group III: Substances presenting low danger

Labels:

Packaging 3

Remarks

SpecialProvisions

Exposure controls / personal protection

Respiratory protection
If product is handled while not enclosed, and if contact may occur:
Wear respirator with an organic vapours and gas filter mask (protection factor 10) conforming to EN140 type A or equivalent.
Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance.

Hand protection
Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness of 0,4 mm, minimum rate of permeability 480 min). Wash when contaminated and dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.

Eye protection
Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).

Skin and body protection
Wear standard coveralls and Category 3 Type 4 suit.
If there is a risk of significant exposure, consider a higher protective type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer.

Stability and reactivity

Reactivity
Stable under normal conditions.

Chemical stability
Stable under recommended storage conditions.

Possibility of hazardous reactions
No dangerous reaction known under conditions of normal use.

Conditions to avoid
Extremes of temperature and direct sunlight.

Incompatible materials
Store only in the original container.

Hazardous decomposition products
No decomposition products expected under normal conditions of use.

Disposal considerations

Waste treatment methods

Product
In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.

Contaminated packaging
Do not re-use empty containers.
Consult state and local regulations regarding the proper disposal of container.

Waste key for the unused product
07 04 00 wastes from the MFSU of organic plant protection products (except 02 01 08 and 02 01 09), wood preserving agents (except 03 02) and other biocides