2-benzyl-2-dimethylamino-4'-morpholinobutyrophenone

Guidance on Safe Use

First-aid measures

Eye contact:

Immediately wash eyes with plenty of running water for at least 15 minutes minimum. Remove contact lenses after the initial 1-2 minutes and

continue flushing for several additional minutes. Occasionally lift the upper and lower eyelids. Seek medical advice if irritation develops and persists.

Skin contact:

Wash affected skin area with plenty of water and soap for at least 15 minutes while removing contaminated clothing and shoes. Seek medical advice if irritation develops and persists.

Ingestion:

Seek medical advice if the victim feels unwell. Wash out mouth with plenty of water and give 2-4 cupfuls of water or milk to drink. Never give anythingby mouth to an unconscious person. Do not induce vomiting.

Inhalation:

Remove the victim from exposure into fresh air if adverse effects (e.g. dizziness, drowsiness or respiratory irritation) occur. If not breathing, give

artificial respiration. If breathing is difficult, give oxygen. Seek medical advice if cough or other symptoms appear.

Fire-fighting measures

Suitable extinguishing media:

Water fog or fine spray, dry chemical fire, carbon dioxide extinguishers and foam; alcohol resistant foam (ACT type) are preferred; general purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.

Unsuitable extinguishing media: Direct water stream.

Exposure hazards (combustion products):

Combustion products may include and are not limited to: Carbon monoxide, carbon dioxide and nitrogen oxides.

Unusual Fire and Explosion Hazards:

Container may rupture from gas generation in a fire situation. Vapours are heavier than air and may travel a long distance and accumulate in low

lying areas.

Special protective equipment for firefighters:

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.

Special methods/instructions:

Keep people away. Isolate fire and deny unnecessary entry. Stay up wind. Keep out of low areas where gases (fumes) can accumulate. Water may not

be effective in extinguishing fire. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all

personnel from the area in case of rising sound from venting safety device or discoloration of the container. Do not use direct water stream. May

spread fire. Eliminate ignition sources. Move container from fire area if this is possible without hazard.

Accidental release measures

Personal precautions:

Wear appropriate personal protective equipment during cleaning. Avoid contact with eyes and skin. Avoid inhalation of dust. Avoid

dust formation. Keep away sources of ignition.

Environmental precautions:

Prevent the material from entering surface water or sanitary sewer system. Do not discharge directly to a water source. If accidental spillage or

washings enter drains or watercourses contact local Environment Agency.

Methods for cleaning up:

Pick up mechanically. Place in suitable and properly labelled waste containers for later disposal. Prevent entry into sewers and waterways. For large

spills: Contain spilled material if possible.

Handling and storage

Handling:

Personal precautions:

Prevent formation of dust. Wear personal protective equipment. Avoid contact with eyes, skin and clothing. Wash thoroughly after

handling. Avoid breathing dust. Dust can form an explosive mixture with air. Take pre-cautionary measure against static charge. Keep away from

sources of heat and ignition.

Technical measures/ Precautions:

Provide good ventilation (local exhaust) of the working area, safety showers and eye wash station near the workplace. Avoid release to the

environment.

Storage:

Technical measures/ Storage conditions:

Keep in the original container. Keep container tightly closed in a cool, dry, well-ventilated place. Keep product away from heat, sparks, flame and

other sources of ignition and out of direct sunlight and away from incompatible materials.

Incompatible products:

Strong oxidizing agents, alkaline and aqueous acids.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3077

Shipping information

Proper shipping name and description:

Environmental Hazardous Substance, Solid, N.O.S.

Chemical name:

2-benzyl-2-dimethylamino-4'-morpholinobutyrophenone

Language:

English

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3077

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3077

Shipping information

Proper shipping name and description:

Environmental Hazardous Substance, Solid, N.O.S.

Chemical name:

2-benzyl-2-dimethylamino-4'-morpholinobutyrophenone

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3077

Shipping information

Proper shipping name and description:

Environmental Hazardous Substance, Solid, N.O.S.

Chemical name:

2-benzyl-2-dimethylamino-4'-morpholinobutyrophenone

Remarks

SpecialProvisions

Exposure controls / personal protection

Exposure controls:

Technical measures:

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to

airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Organisational measures:

Only personnel who have received appropriate training and are authorized are allowed to handle the substance.

Personal protective equipment:

Respiratory protection:

Use a properly fitted, air-purifying or air-fed respirator complying with NIOSH-approved respirator with minimum APF 10. For emergency conditions

use an approved positive-pressure self-contained breathing apparatus.

Recommended: Dust mask type N95.

Hand protection:

After contamination with product change the gloves immediately and dispose them off according to relevant national and local regulations.

Recommended: Chemical resistant protective gloves (EN 374), Protective index 6, corresponding > 480 minutes of permeation time according to

EN 374.

Eye protection:

Safety glasses with side-shields (frame goggles) (e.g. EN 166).

Skin and body protection:

Wear chemical-resistant protective clothing.

Hygiene measures:

Keep away from foodstuffs, drinks and tobacco. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking

and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Environmental exposure controls:

Procedural and/or control technologies are used to minimize emissions and the resulting exposure during cleaning and maintenance procedures.

Transfer waste gases to a combustion unit or to a powder separator.

Do not apply industrial sludge to natural soils. Sealing of all relevant soil surfaces in the facility.

Stability and reactivity

Chemical Stability: Stable under normal conditions and recommended use.

Conditions to be avoided: Static discharges. Keep product away from heat, sparks, flame and other sources of ignition. Avoid direct sunlight and UV

light.

Materials to avoid: Strong oxidizing agents, alkaline and strong acids.

Hazardous polymerization: Will not occur.

Hazardous decomposition products: Thermal decomposition and burning may produce carbon monoxide, nitrogen oxides and other toxic gases

and vapors.

Disposal considerations

Waste from residues:

Any disposal practices must be in compliance with all national and provincial laws and any municipal or local by-laws governing hazardous waste.

For used, contaminated and residual materials additional evaluations may be required. Do not dump into any sewers, on the ground, or into any body

of water.

Container:

Containers should be cleaned by appropriate method and then re-used or disposed by landfill or incineration as appropriate, in accordance with

local and national regulations. Do not remove label until container is thoroughly cleaned.