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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
4th December 2012 (experimental phase start) to 10 January 2013 (experimental phase end)
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: see 'Remark'
Remarks:
Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results. The study report was conclusive, done to a valid guideline and the study was conducted under GLP conditions. The study meets the criteria for classification as reliable without restriction according to Klimisch et al (1997).

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2013
Report date:
2013

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
no
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
4-(naphthalen-2-yl)-1,3-thiazol-2-amine
EC Number:
606-740-6
Cas Number:
21331-43-1
Molecular formula:
C13H10N2S
IUPAC Name:
4-(naphthalen-2-yl)-1,3-thiazol-2-amine
Test material form:
solid: particulate/powder
Remarks:
migrated information: powder
Details on test material:
Identification: 4-(2-naphthalenyl)-2-thiazolamine
Description: off white powder
purity 98.8%

Results and discussion

Relative self-ignition temperature (solids)
Remarks on result:
other: None below its melting temperature

Any other information on results incl. tables

Results

See the illustration(picture/graph) section for the temperature/time curve.

Observations after the test

The test item was an off white powder.Whilst heating the test item, no relevant exothermic reaction/self-heating of the sample was been observed.The temperature/time curve is shown below. On completion of the test, the cube was empty, long white needle shaped crystals were observed on the oven door seal.

Applicant's summary and conclusion

Conclusions:
The test item has been determined not to have a relative self-ignition temperature below its melting temperature.
Executive summary:

Introduction

Hazardous physico-chemical properties of the test item have been determined. Methods employed were designed to be compatible with those specified in Commission Regulation (EC) No 440/2008 of 30 May 2008, Part A: Methods for the determination of physico-chemical properties.

Method

The test item was heated in an oven and the relative self ignition temperature determined. Testing was conducted using a procedure designed to be compatible with Method A16 Relative Self-Ignition Temperature for Solids ofCommissionRegulation (EC) No 440/2008 of 30 May 2008.

Results

Whilst heating the test item, no relevant exothermic reaction/self-heating of the sample was been observed. On completion of the test, the cube was empty, long white needle shaped crystals were observed on the oven door seal.

Conclusion

The test item has been determined not to have a relative self-ignition temperature below its melting temperature.