Registration Dossier

Administrative data

First-aid measures

General:
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance.
Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.

Description of first aid measures:
Inhalation:
Inhalation is possible if aerosols, mists, dusts, or smoke form.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.

Skin Contact:
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.

Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
In case of persistent discomfort: Consult an ophthalmologist.

Ingestion:
Rinse mouth.
Immediately give large quantities of water to drink.
Obtain medical attention.

Most important symptoms and effects, both acute and delayed:
None known.

Indication of any immediate medical attention and special treatment needed:
Hazards:
Other dangerous properties can not be excluded.

Treatment:
This product has not been completely analyzed yet and all health hazards might not be known.

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media:
All extinguishing substances suitable.

Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture:
May be released in case of fire:
Organic, nitrogenous and sulphurous products of decomposition.
Carbon monoxide, nitric oxides, sulphur dioxide.
Carbon Dioxide.

Advice for firefighters:
Special fire fighting procedures:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
Use water spray to cool unopened containers.
Fire residues should be disposed of in accordance with the regulations.
Pay attention to self-protection.
Keep out unprotected persons.

Special protective equipment for fire-fighters:
In case of fire: full protective suit and wear a self contained respiratory apparatus

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Keep unauthorized personnel away.

For non-emergency personnel:
No data available.

For emergency responders:
No data available.

Environmental Precautions:
Observe regulations on prevention of water pollution (check, dam up, cover up).
Do not allow entrance in sewage water, soil, stretches of water, drainage systems, surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and material for containment and cleaning up:
Pack and label wastes like the pure substance.
Do not detach label from the delivery containers prior to disposal.
Disposal according to local authority regulations.

Reference to other sections:
Wear personal protective equipment; see Exposure controls/personal protection.

Handling and storage

Precautions for safe handling:
All precautionary measures indicated have to be observed.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Regular safety training is a must.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Ensure that apparatus and pipelines are free from leaks.
Do not ventilate into the open.
Dedicated loading/unloading stations required.
The personal protective equipment used must meet the requirements of Regulation (EU) 2016/425 and amendments (CE certification).
It should be defined in the work place in the form of a risk analysis according to Regulation (EU) 2016/425 and amendments.

Conditions for safe storage, including any incompatibilities:
Protect from sunlight, warmth and heat.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
Keep at temperatures of between 2 °C and 8 °C.
Observe prohibition against storing together!
Normal measures for preventive fire protection.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Further information:
VDI 2263 "Dust fires and dust explosions; dangers, evaluation, preventive measures."

Storage Class: 13: Non-combustible solids

Transport information

Land transport (ADR/RID)

UN number:
UN 2811
Shippingopen allclose all
Class:
6.1
Classification code:
T2
Packaging group:
I
Labels:
6.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 2811
Shippingopen allclose all
Class:
6.1
Classification code:
T2
Packaging group:
I
Labels:
6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 2811
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. (cyclopropyl[4-(phenylmethyl)-1-piperazinyl]methanone hydrochloride)
Chemical name:
(cyclopropyl[4-(phenylmethyl)-1-piperazinyl]methanone hydrochloride)
Class:
6.1
Packaging group:
I
EmS code:
F-A, S-A
Labels:
6.1
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 2811
Proper shipping name and description:
Toxic solid, organic, n.o.s. (cyclopropyl[4-(phenylmethyl)-1-piperazinyl]methanone hydrochloride)

Chemical name:
(cyclopropyl[4-(phenylmethyl)-1-piperazinyl]methanone hydrochloride)
Class:
6.1
Packaging group:
I
Labels:
6.1
Remarks
IATA (Cargo aircraft only):
Remarks:
ERG-Code 6F

IATA (Passenger and cargo aircraft):
Remarks :
ERG-Code 6F


Additional transport information

Additional transport information
Special precautions for user:
Remarks :
Keep separate from foodstuffs, luxury foods, feedstuffs

The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet.
Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.

Transport in bulk according to Annex II of Marpol and the IBC Code:
Not applicable for product as supplied.



Exposure controls / personal protection

Control Parameters:
Occupational Exposure Limits:
None of the components have assigned exposure limits.

DNEL-Values:
Remarks:
No substance-related safety assessment is necessary / has been conducted for this product.

PNEC-Values:
Remarks:
No substance-related safety assessment is necessary / has been conducted for this product.

Exposure controls:
Appropriate Engineering Controls:
Provide for installation of emergency shower and eye bath.
All precautionary measures indicated have to be observed.
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Do not lead exhaust air back to workplace areas unfiltered.
Exhaust filter or scrubber.
Exhaust air filter (HEPA-filter).
Do not add wastewater to a biological wastewater treatment plant.
In case of dissolved solids:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
Ensure that extracted air cannot be returned to the workplace through the ventilation system.
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.

Individual protection measures, such as personal protective equipment:

Eye/face protection:
Safety glasses with side-shields conforming to EN166
or
Accidental release measures close-fitting protective goggles (e.g. closed goggles)

Hand Protection:
Material: Nitrile.
Glove thickness: 0.11 mm
Guideline: DIN EN 374

Material: Nitrile/Chloroprene
Glove thickness: 0.65 mm
Guideline: DIN EN 374
Additional Information: Accidental release measures

Additional Information:
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials.
Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to EN 374 due to the many different influential factors involved (e.g. temperature).

Skin and Body Protection:
Suitable protective clothing - Use disposable clothing if appropriate.

Respiratory Protection:
Full mask, particle filter P3, colour code: white.

Accidental release measures:
In the case of respirable dust, use self-contained breathing apparatus.
Note time limit for wearing respiratory protective equipment.

Hygiene measures:
Take off contaminated clothing and wash it before reuse.
Do not eat, drink, smoke, or sniff while at work.
Wash your hands and/or face before breaks and before termination of work.
Preventive skin protection is recommended.
Use barrier cream regularly.

Environmental Controls:
In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease emissions to acceptable values.

Stability and reactivity

Reactivity:
No further information available

Chemical Stability:
No further information available

Possibility of hazardous reactions:
No further information available

Conditions to avoid:
No further information available

Incompatible Materials:
No further information available

Hazardous Decomposition Products:
No further information available

Disposal considerations

Waste treatment methods:
General information:
No data available.

Disposal methods:
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Do not add wastewater to a biological wastewater treatment plant.
Bring used exhaust air filter for incineration.
Disposal according to local authority regulations.
Pack and label wastes like the pure substance.
Do not detach label from the delivery containers prior to disposal.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.

Contaminated Packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.