Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

Description of first aid measures
If inhaled :
If breathed in, move person into fresh air.
Artificial respiration and/or oxygen may be necessary.
Take victim immediately to hospital.

In case of skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and water.
Consult a physician.

In case of eye contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses.
Consult a physician.

If swallowed:
If swallowed, rinse mouth with water (only if the person is conscious).
Do NOT induce vomiting.
Call a physician immediately.

Most important symptoms and effects, both acute and delayed
Symptoms: Ingestion may provoke the following symptoms: calming, Lack of coordination

Indication of any immediate medical attention and special treatment needed
Treatment: Treat symptomatically.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Water mist
Dry powder
Foam
Carbon dioxide (CO2)
Sand
Aqueous film forming foam (AFFF).

Unsuitable extinguishing media: Water spray jet

Special hazards arising from the substance or mixture
Specific hazards during fire-fighting: Risk of dust explosion.

Hazardous combustion products: Nitrogen oxides (NOx), Carbon oxides

Advice for firefighters
Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus.

Further information: Avoid dust formation.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Personal precautions :
Avoid dust formation.
Avoid breathing dust.
Evacuate personnel to safe areas.
Keep away from open flames, hot surfaces and sources of ignition.

Environmental precautions:
Should not be released into the environment.
Do not flush into surface water or sanitary sewer system.

Methods and material for containment and cleaning up
Methods for cleaning up:
Large spills: Sweep up or vacuum with HEPA filter or via wet cleaning into suitable containers for disposal.
Pick up and arrange without creating dust. Keep in properly labelled containers.
Small spills: Moisten a towel, cover the spill, pick up the spill or use HEPA vacuum.
Large spills + Small spills: Keep in suitable, closed containers for disposal. Treat recovered material as described in the section "Disposal considerations".

Handling and storage

Precautions for safe handling
Advice on safe handling: Ensure all equipment is electrically grounded before beginning transfer operations.
Advice on protection against fire and explosion: Avoid dust formation.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
Dust explosion class: St1

Conditions for safe storage, including any incompatibilities
Recommended storage temperature: 15 - 25 °C

Transport information

Land transport (ADR/RID)

UN number:
UN 3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Chemical name:
(N-(dihydro-3,3-diphenyl-2(3H)-furanylidene)-N-methylmethanaminium bromide.)
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Special Provisions:
Special Provision 375: Environmentally Hazardous Substances/Marine Pollutants, classified under UN 3077 or UN 3082, packaged in single or combination packagings containing a net quantity per single of inner packaging of 5L or less for liquids or having a net mass per single of inner packaging of 5kg or less for solids are not subject to the ADR/RID/ADN/IMDG/IATA DGR provided the packagings meet the general requirements of 4.1.1.1, 4.1.1.2, and 4.1.1.4 to 4.1.1.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Inland waterway transport (ADN(R))

UN number:
UN 3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Chemical name:
(N-(dihydro-3,3-diphenyl-2(3H)-furanylidene)-N-methylmethanaminium bromide.)
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Remarks
Special Provision 375: Environmentally Hazardous Substances/Marine Pollutants, classified under UN 3077 or UN 3082, packaged in single or combination packagings containing a net quantity per single of inner packaging of 5L or less for liquids or having a net mass per single of inner packaging of 5kg or less for solids are not subject to the ADR/RID/ADN/IMDG/IATA DGR provided the packagings meet the general requirements of 4.1.1.1, 4.1.1.2, and 4.1.1.4 to 4.1.1.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Marine transport (IMDG)

UN number:
UN 3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Chemical name:
(N-(dihydro-3,3-diphenyl-2(3H)-furanylidene)-N-methylmethanaminium bromide.)
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Marine pollutant
Remarks
2.10.2.7: Environmentally Hazardous Substances/Marine Pollutants, classified under UN 3077 or UN 3082, packaged in single or combination packagings containing a net quantity per single of inner packaging of 5L or less for liquids or having a net mass per single of inner packaging of 5kg or less for solids are not subject to the IMDG provided the packagings meet the general requirements of 4.1.1.1, 4.1.1.2, and 4.1.1.4 to 4.1.1.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Air transport ICAO/IATA

UN number:
UN 3077
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s.
Chemical name:
(N-(dihydro-3,3-diphenyl-2(3H)-furanylidene)-N-methylmethanaminium bromide.)
Class:
9
Packaging group:
IATA (Cargo)
Packing instruction (cargo aircraft): 956
Packing instruction (LQ): Y956
Packing instruction (EQ): E1

IATA (Passenger)
Packing instruction (passenger aircraft): 956
Packing instruction (LQ): Y956
Labels:
9
Remarks
Special Provision A197: Environmentally hazardous substances, classified under UN 3077 or UN 3082, when transported in single or combination packagings containing a net quantity per single or inner packaging of 5 L or less for liquids or having a net mass of 5 kg or less for solids, are not subject to any other provisions of the IATA DGR provided the packagings meet the general provisions of IATA DGR 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of IATA DGR §2.6.10 are met.
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering measures
Engineering controls should be used as the primary means to control possible exposures. Use process enclosures, local exhaust ventilation or other engineering controls to keep exposure levels below recommended exposure limits.
All personal protective equipment should be based on a risk assessment. Consult a Environment Health Safety expert if necessary.

Personal protective equipment
Eye protection: Face-shield

Hand protection Material: Nitrile rubber. remark: Impervious gloves. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, dura-tion of contact).

Skin and body protection: closed work clothing disposable one-piece overall

Respiratory protection:
Engineering controls should always be the primary method of controlling exposures.
If respiratory protective equipment is needed for certain activi-ties, the type as well as the corresponding protection factor will depend upon the risk assessment and air concentrations, hazards, physical and warning properties of substances present.
Use only respiratory protection that conforms to international/ national standards.
Suitable mask with particle filter P3

Protective measures: The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Stability and reactivity

Reactivity: None reasonably foreseeable.

Chemical stability: Stable under recommended storage conditions.

Possibility of hazardous reactions: Risk of dust explosion.

Conditions to avoid: To avoid thermal decomposition, do not overheat. Heat, flames and sparks.

Materials to avoid: Strong oxidizing agents

Hazardous decomposition products: Carbon oxides, Nitrogen oxides (NOx)

Disposal considerations

Product: In accordance with National, Federal, State and Local regulations.