Registration Dossier

Administrative data

First-aid measures

General advice:
Under the shower: Take off immediately all contaminated clothing. including shoes.
Inhalation:
Inhalation of mists Move patient from contaminated area to fresh air. Oxygen or artificial respiration if needed. Keep under medical
surveillance. In case of problems : Hospitalise.
Skin contact:
Wash immediately, abundantly and thoroughly with water. Consult a physician. In case of extensive burns, hospitalize. In the case of skin
irritation or allergic reactions see a physician.
Eye contact:
Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Consult an ophthalmologist immediately.
Ingestion:
Do not induce vomiting, rinse mouth and lips with plenty of water if the subject is conscious, then hospitalize.
Protection of first-aiders:
If entering a saturated atmosphere, wear a self contained breathing apparatus. Protective suit

Fire-fighting measures

Suitable extinguishing media: Water spray, Foam, Dry powder, Carbon dioxide (CO2)
Unsuitable extinguishing media: High volume water jet

Special hazards arising from the substance or mixture:
Flammable., Thermal decomposition giving toxic products, Ammonia, Carbon oxides, Formation of toxic products through combustion:,
Nitriles, Cyanides, Possible re-ignition of vapours from a distance

Advice for firefighters:
Specific methods:
Use water spray to cool unopened containers. Ensure containers can be rapidly moved. In case of fire nearby, remove exposed containers.
Prohibit all sources of sparks and ignition - Do not smoke.
Special protective actions for fire-fighters:
In the event of fire, wear self-contained breathing apparatus. Complete suit protecting against chemicals

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment. Prohibit contact with skin and eyes and inhalation of vapours. Ensure adequate ventilation. Evacuate
personnel to safe areas. Prohibit all sources of sparks and ignition - Do not smoke. Prohibit inhalation of vapours. Beware of vapours
accumulating to form explosive concentrations. Vapours can accumulate in low areas.

Environmental precautions:
Prevent product from entering drains. Dam up with sand or inert earth (do not use combustible materials). Should not be released into the
environment.

Methods and materials for containment and cleaning up:
Recovery:
Pump into a labelled inert emergency tank. Moist product : absorb the remainder with an inert absorbent material. Capture the gas with fine
water spray (scrubbing), collect and treat contaminated water.
Neutralisation:
Neutralize with a sodium bisulphate solution.
Elimination:
Destroy the product by incineration (in accordance with local and national regulations).

Handling and storage

Precautions for safe handling:
Technical measures/Precautions:
Storage and handling precautions applicable to products: Liquid. Flammable. Corrosive. Toxic. Sensitizing. Provide appropriate exhaust
ventilation at machinery.
Safe handling advice:
Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Open
drum carefully as content may be under pressure. Provide fire-blanket nearby. Provide a catch-tank in a bunded area. Provide impermeable
floor. Provide waterproof electrical equipment. Provide showers, eye-baths. Provide water supplies near the point of use. Provide electrical
earthing of equipment and electrical equipment usable in explosive atmospheres. Prohibit all sources of sparks and ignition - Do not smoke.
Use only in an area containing explosion proof equipment. Do not use air for transfers

Hygiene measures:
Prohibit contact with skin and eyes and inhalation of vapours.
Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.


Conditions for safe storage, including any incompatibilities:
Keep in a dry, cool and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Store protected from moisture and heat. Remove all sources of ignition.
Do not store above: 50 °C
Incompatible products:
Strong oxidizing agents, Perchlorates, Nitrates, Peroxides, Strong acids, Water, Halogens, Product likely to react violently in alkaline
environment, Nitric acid, Oxygen, Nitrites

Packaging material:
Recommended: Ordinary steel
To be avoided: Light metals and alloys (corrosion)

Transport information

Land transport (ADR/RID)

UN number:
2733
Proper shipping name and description:
AMINES, FLAMMABLE, CORROSIVE, N.O.S.(n-
HEPTYLAMINE)
Chemical name:
n- HEPTYLAMINE)
Class:
3
Packaging group:
III
Labels:
3+8
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2733
Proper shipping name and description:
AMINES, FLAMMABLE, CORROSIVE, N.O.S.(n-
HEPTYLAMINE)
Chemical name:
n- HEPTYLAMINE)
Class:
3
Packaging group:
III
Labels:
2 + 8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2733
Proper shipping name and description:
AMINES, FLAMMABLE, CORROSIVE, N.O.S.(n-
HEPTYLAMINE)
Chemical name:
(n- HEPTYLAMINE)
Class:
3
Packaging group:
III
EmS code:
F-E, S-C
Labels:
3 + 8
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2733
Proper shipping name and description:
AMINES, FLAMMABLE, CORROSIVE, N.O.S.(n-
HEPTYLAMINE)
Chemical name:
AMINES, FLAMMABLE, CORROSIVE, N.O.S.(n-
HEPTYLAMINE)
Class:
3
Packaging group:
III
Labels:
3 + 8
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

General protective measures: Provide sufficient air exchange and/or exhaust in work rooms.
Personal protective equipment:
Respiratory protection: High concentrations or prolonged activity: Self contained Breathing Apparatus
Low concentrations or short activity: Mask with specific cartridge Recommended Filter type:
A2B2E2K2P3
Hand protection: Splash contact, intermittent and prolonged PVC gloves
According to permeation index EN 374: 1 (time elapsed > 10 mins)
Eye/face protection: Safety glasses with side-shields
Skin and body protection: At the workplace : Protective clothing (cotton)
Intervention at incident: Combination with delayed penetration

Stability and reactivity

Possibility of hazardous reactions:
Further information: Stable under recommended storage conditions.
Conditions to avoid: Temperatures above 50 °C
Protect from heat. Exposure to moisture.

Incompatible materials to avoid:
• Violent reaction and flammability with :, Oxidizing agents, Nitrates, Peroxides, • Very exothermic reaction and possibility of spitting with :,
Strong acids, Halogens, Product likely to react violently in alkaline environment, • Formation of toxic products (n-nitrosamines) with:, Nitrous
acid and other nitrosating agents, Nitrites, Oxygen, • Very exothermic reaction with :, Water, Corrosion with : light metals and alloys

Hazardous decomposition products:
Thermal decomposition giving toxic and corrosive products :, Ammonia, Carbon oxides, Nitriles, Cyanides

Disposal considerations

Disposal of product: Neutralize with a sodium bisulphate solution. Destroy the product by incineration (in accordance with
local and national regulations).
Disposal of packaging: Purging of residual gases in empty packaging is obligatory before recovery. Destroy packaging by
incineration at an approved waste disposal site. Clean container with water. Recover waste water for
processing later.