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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Vapour pressure

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Administrative data

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Deviations:
no
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Deviations:
not applicable
GLP compliance:
yes
Type of method:
effusion method: vapour pressure balance
Temp.:
20 °C
Vapour pressure:
0 Pa
Remarks on result:
other: Confidence limit: 3.7x 10E-9 - 3.6x10E-8 Pa
Key result
Temp.:
25 °C
Vapour pressure:
0 Pa
Remarks on result:
other: Confidence limit: 1.0x 10E-8 - 8.7x10E-8 Pa
Temp.:
30 °C
Vapour pressure:
0 Pa
Remarks on result:
other: Confidence limit: 2.6x 10E-8 - 1.9x10E-7 Pa

The vapour pressures were calculated for 20, 25 and 30 °C using a semilogarithmic linear regression based on the Antoin equation.

Conclusions:
The vapour pressure was determined at 25 °C to be 3x10E-08Pa (confidence limit: 1.0x10E-08and 8.7x10E-08Pa).                                
Executive summary:

According to the OECD Testing Guideline No.104 the temperature dependence of the vapour pressure was determined with the Knudsen effusion method using a vapour pressure balance in the temperature range 100 to 135 °C. For measurement, the vapour jet of the test substance leaving a heatable Knudsen cell through an aperture of known size under high vacuum conditions is condensed on the cooled scale pan of a precision "Cahn"-microbalance. The evaporation rate is determined from the increase in weight per unit time from which the vapour pressure is calculated with the Hertz Knudsen Langmuir equation. The vapour pressure was determined at 25 °C to be 3x10-08Pa (confidence limit: 1.0x10-08and 8.7x10-08Pa). The Henry constant was calculated to be 1.1x10-9at 25 °C. Thus the substance is to be considered non-volatile in aqueous solution.

Description of key information

The vapour pressure was determined at 25 °C to be 0.00000003Pa (95%confidence interval: 0.00000001 - 0.000000087 Pa). 

Key value for chemical safety assessment

Vapour pressure:
0 Pa
at the temperature of:
25 °C

Additional information