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Diss Factsheets

Physical & Chemical properties

Auto flammability

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Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
14 April 2016 - 22 April 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
2008
Deviations:
no
Qualifier:
equivalent or similar to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Version / remarks:
2003-05
Deviations:
no
GLP compliance:
no
Key result
Auto-ignition temperature:
340 °C
Atm. press.:
>= 999.3 - <= 1 019.1 hPa

Table 1. Auto-ignition results for main test

Test number  Barometric pressure range (hPa)  Auto-ignition temperature (°C)  Time lag (s)
 1  999.3 -1018.8  345  7
 2  1019.1  346  6
 3  1010.5 -1012.1  348  6
Conclusions:
The auto-ignition temperature for the test item was determined to be 340°C.
Executive summary:

The auto-ignition temperature for the test item was determined to be 340°C. The lowest auto-ignition temperature of the test item was determined to be 345°C. According to standard DIN 51794:2003 -05, the lowest measured temperature at which an ignition is observed is rounded to the next lower number divisible by 5 for safety reasons. This study is reliable without restrictions (Klimisch 1) as it was performed according to EU Method A.15. Although the study was not performed in compliance with GLP, the test facility is GLP-compliant.

Description of key information

The auto-ignition temperature for the test item was determined to be 340°C. The lowest auto-ignition temperature of the test item was determined to be 345°C. According to standard DIN 51794:2003 -05, the lowest measured temperature at which an ignition is observed is rounded to the next lower number divisible by 5 for safety reasons.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
340 °C

Additional information

This study is reliable without restrictions (Klimisch 1) as it was performed according to EU Method A.15 (2017). Although the study was not performed in compliance with GLP, the test facility is GLP-compliant. According to ECHA guidance "Guidance on Information Requirements and Chemical Safety Assessment; Chapter R.7A: Endpoint specific guidance" (December 2016), the auto-ignition temperature for liquids is not used directly for classification and labeling according to regulation (EC) 1272/2008, however it can be used in the chemical safety assessment.