Registration Dossier

Administrative data

First-aid measures

4.1 Description of first aid measures:
In all cases of doubt, or when symptoms persist, seek medical attention.
4.1.1 In case of inhalation:
Remove patient to fresh air.
4.1.2 In case of skin contact:
Wash skin with plenty of water, and soap if available, for several minutes. Seek medical attention if irritation develops or persists.
4.1.3 In case of eyes contact:
Rinse eyes with plenty of water for several minutes. Seek medical attention if irritation develops.
4.1.4 In case of ingestion:
Seek medical attention.
4.2 Most important symptoms and effects, both acute and delayed:
Harmful if swallowed. May cause an allergic skin reaction.
4.3 Indication of any immediate medical attention and special treatment needed:
If skin irritation or rash occurs, get medical advice/attention.

Fire-fighting measures

5.1 Extinguishing media:
Suitable extinguishing media: Water, foam and dry powder may be used.
Unsuitable extinguishing media: Not available.
5.2 Special hazards arising from the
substance or mixture Products of combustion may contain oxides of carbon and nitrogen.
5.3 Advice for firefighters: Firefighters must wear fire resistant protective equipment. Wear approved respirator and protective gloves.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:
6.1.1 For non-emergency personnel: Remove ignition sources. Provide adequate ventilation. Avoid inhalation dust. Avoid skin and eye contact. For personal protection see Section 8.
6.1.2 For emergency responders: Wear an appropriate NIOSH/MSHA approved respirator if dust is generated.
6.2 Environmental Precautions: Avoid disposing into drainage/sewer system or directly into the aquatic environment.
6.3 Methods for Containment and Cleaning
up: Carefully shovel up spills (avoiding generation of dust) and place in labelled containers for disposal or recycling. Dispose of in accordance with local regulations at a suitable facility.
6.4 Reference to other sections: See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

Handling and storage

7.1 Precautions for safe handling:
7.1.1 Protective measures: Rubber/plastic gloves and safety goggles are worn to prevent skin and eye contact. Dust filter masks are worn where dust or particulates are generated by the use process. General industrial hygiene practices of avoiding contact with eyes, skin and clothing, and washing thoroughly after handling, are followed. Local exhaust ventilation is used.
7.1.2 Advice on general occupational
hygiene: Do not eat, drink and smoke in work areas. Wash hands after use. Remove contaminated clothing and protective equipment before entering eating areas.
7.2 Conditions for safe storage, including
any incompatibilities: Store in a cool, dry place in closed, sealed containers. Packaging of the substance and or preparation: Fiber drums of 50 kg net weight with polyethylene inner bags.
7.3 Specific end use(s): Not applicable.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

8.1 Control parameters:
8.1.1 Occupational exposure limits: Not available.
8.1.2 Additional exposure limits under the
conditions of use: Not available.
8.1.3 DNEL/DMEL and PNEC-Values: Not available.
8.2 Exposure controls:
8.2.1Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
8.2.2 Individual protection measures, such as personal protective equipment:
Eye/face protection: Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Hand protection: Handle with gloves. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body protection: Wear suitable protective clothing to prevent skin exposure.
Respiratory protection: For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator. For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Thermal hazards: Wear suitable protective clothing to prevent heat.
8.2.3 Environmental exposure controls: Avoid discharge into the environment.
According to local regulations, Federal and official regulations.

Stability and reactivity

10.1 Reactivity: The substance is stable under normal storage and handling conditions.
10.2 Chemical stability: Stable at room temperature in closed containers under normal storage and handling conditions.
10.3 Possibility of hazardous reactions: No dangerous reactions known.
10.4 Conditions to avoid: Incompatible materials.
10.5 Incompatible materials: Strong oxidizing agents.
10.6 Hazardous decomposition products: Oxides of carbon and nitrogen.

Disposal considerations

13.1 Waste treatment methods: Due to the high risk of contamination recycling/recovery is not recommended. Waste disposal in accordance with regulations (most probably controlled incineration).