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Diss Factsheets

Administrative data

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
The study was conducted between 21 March 2016 and 8 April 2016.
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2016
Report date:
2017

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Deviations:
no
GLP compliance:
no
Remarks:
study done in an internal lab

Test material

Constituent 1
Chemical structure
Reference substance name:
4-(tricyclo[5.2.1.02,6]dec-8-ylidene)butyraldehyde
EC Number:
250-078-7
EC Name:
4-(tricyclo[5.2.1.02,6]dec-8-ylidene)butyraldehyde
Cas Number:
30168-23-1
Molecular formula:
C14H20O
IUPAC Name:
4-[(8Z)-tricyclo[5.2.1.0^{2,6}]decan-8-ylidene]butanal
Test material form:
liquid
Specific details on test material used for the study:
Lot No.: VE00405355
Aspect: colourless to pale yellow liquid
Purity: 98.0% (sum of two isomers)

Results and discussion

Auto-ignition temperature (liquids / gases)
Key result
Auto-ignition temperature:
280 °C
Atm. press.:
101.3 kPa

Applicant's summary and conclusion

Conclusions:
The lowest temperature giving a positive effect was 284 °C. The injected volume was 100 µL, the ignition delay was 5 s. At a temperature of 279 °C no ignition was observed. Therefore, after rounding-off to the next lower multiple of 5 °C, the auto-ignition of Dupical was 280 ± 10 °C.
Executive summary:

The auto-ignition temperature of Dupical was determined in a SUR BERLIN oven, equipped with a 250 mL glass ignition vessel according to DIN 51794.

The lowest temperature giving a positive effect was 284°C. The injected volume was 100µL, the ignition delay was 5 s. At a temperature of 279°C no ignition was observed.

Therefore, after rounding off to the next lower multiple of 5°C the auto-ignition temperature of Dupical was 280±10°C.