Reaction product of {Sulfonic acid derivatives of [4-(aminoalkylamino)-6-substituted-1,3,5-triazin-2-ylamino]benzene}, ammonia water, sodium chloride and [poly(1~4)chlorosulfonyl(poly(1~4) benzo-poly(3~0)pyrido-5,10,15,20-tetraazaporphyrinato- N21,N22,N23,N24)]copper(II)

Auto flammability

Administrative data

Endpoint:

relative self-ignition temperature (solids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

Testing was conducted between 15 March 2011 and 28 April 2011.

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

other: Study conducted to GLP and in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not effect the quality of the relevant results.

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2011

Report date:

2011

Materials and methods

Test guideline

Qualifier:

according to guideline

Guideline:

EU Method A.16 (Relative Self-Ignition Temperature for Solids)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Test material

Test material information

Constituent 1

Test material form:

solid: particulate/powder

Remarks:

migrated information: powder

Details on test material:

Identification: TM10-099
Description: dark blue powder
Batch number: MB-1
Date received: 4 March 2011
Expiry date: 4 March 2012
Storage conditions: room temperature in the dark

Results and discussion

Relative self-ignition temperature (solids)

Relative self-ignition temperature:

> 400 °C

Remarks on result:

other: The test item has been determined not to have a relative self-ignition temperature below 400 °C.

Any other information on results incl. tables

The temperatureltime curve indicates that self-ignition of the test item did not occur as the oven temperature was increased to 400°C. Once the oven temperature has reached 400 °C this is deemed to be the end of the testing period. However, the temperature/time

curve shows that the oven temperature was maintained at 400 °C for an additional approximately 6 hours. After the oven had been at 400 °C for approximately 2 hours, the temperature of the sample increased to more than 500 °C. This thermal event is not regarded as self-ignition because it occurred after the testing period.

At the end of the test, the cube contained a grey/green partly fused solid.

Applicant's summary and conclusion

Conclusions:

The test item has been determined not to have a relative self-ignition temperature below 400 °C.

Executive summary:

The self-ignition temperature of the test item TM10-099 was determined in a valid GLP study. Testing was conducted using a method designed to be compatible with EU Method A.16.

The test item was heated in an oven and the relative self-ignition temperature determined. The oven temperature was increased from ambient temperature to 400 °C at a rate of 0.5 °C/min.

The test item has been determined not to have a relative self-ignition temperature below 400°C.