Registration Dossier

Administrative data

First-aid measures

Description of first aid measures:
Symptoms of poisoning may appear several hours later.
Remove contaminated or saturated clothing immediately and dispose of safely.

Inhalation:
Provide fresh air, seek medical advice if necessary.

Skin contact:
Wash off with soap and water.

Eye contact:
Rinse immediately with plenty of water for 15 minutes and seek advice of an eye specialist.

Ingestion:
Flush mouth immediately, then drink plenty of water, avoid vomiting, consult physician.

Indication of any immediate medical attention and special treatment needed:
Treatment of symptoms.

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media:
Water spray, foam, CO2, dry powder.

Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture:
In the case of fire, the following hazardous smoke fumes may be produced: hydrogen chloride, oxides of phosphorus, carbon monoxide.

Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Keep out unprotected persons.
Wear a self contained respiratory apparatus full protective suit.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Keep out unprotected persons.

Environmental precautions:
Prevent substance from entering soil, natural bodies of water and sewer systems.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and material for containment and cleaning up:
Collect up material.
Transfer into suitable containers for recovery or disposal.
Disposal according to local authority regulations.
Avoid dust formation.

Handling and storage

Precautions for safe handling:
Refill and handle product only in closed system.
Ensure that apparatus and pipelines are free from leaks.
Do not ventilate into the open.
Provide sufficient ventilation and exhaust at the workplace.
Trained personnel must be used.
Avoid dust formation.
Keep in a dry, cool place.

Conditions for safe storage, including any incompatibilities:
Advice on protection against fire and explosion:
Keep away from combustion sources such as sparks, flames and unprotected light sources.
When using do not smoke.
Take precautionary measures against static charges, keep away from sources of ignition.

Storage:
Keep in a dry, cool and well-ventilated place.

Further information:
Protect against humid air and water.
Keep away from oxidizing agents.

Advice on common storage:
Protect against oxidizing agents, humid air and water.

Transport information

Land transport (ADR/RID)

UN number:
UN 2811
Shippingopen allclose all
Class:
6.1
Classification code:
T2
Packaging group:
II
Labels:
6.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 2811
Shippingopen allclose all
Class:
6.1
Classification code:
T2
Packaging group:
II
Labels:
6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 2811
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. ((tert-Butoxycarbonylmethyl)-triphenylphosphonium chloride (DCM))
Chemical name:
(tert-Butoxycarbonylmethyl)-triphenylphosphonium chloride (DCM)
Class:
6.1
Packaging group:
II
EmS code:
F-A, S-A
Labels:
6.1
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 2811
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. ((tert-Butoxycarbonylmethyl)-triphenylphosphonium chloride (DCM))
Chemical name:
(tert-Butoxycarbonylmethyl)-triphenylphosphonium chloride (DCM)
Class:
6.1
Packaging group:
II
Labels:
6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls:
Engineering measures:
Refill and handle product only in closed system.
Provide appropriate exhaust ventilation at machinery.
Do not add wastewater to a biological wastewater treatment plant.
All precautionary measures indicated have to be observed.
Provide for installation of emergency shower and eye bath.

In case product dust is released:
Exhaust ventilation equipped with filters.

Exposure controls:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.

Personal protective equipment:
Respiratory protection:
Accidental release measures:
In the case of respirable dust, use self-contained breathing apparatus.

Hand protection:
Protective gloves - select suitable protective gloves from the glove chart.

Eye protection:
Safety glasses with side-shields conforming to EN166.

Accidental release measures:
Close-fitting protective goggles (e.g. closed goggles).

Skin and body protection:
Long sleeved clothing.

Hygiene measures:
Keep away from food, drink and animal feedingstuffs.
Wash hands before breaks and at the end of workday.
Avoid contact with skin and eyes.
Remove immediately all contaminated clothing.

Protective measures:
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
Regular safety training is a must.
All precautionary measures indicated have to be observed.

Stability and reactivity

Possibility of hazardous reactions:
No dangerous reaction known under conditions of normal use.
No special measures are required.

Conditions to avoid:
No decomposition if used as directed.
Take precautionary measures against static discharges.

Incompatible materials :
Amines, Oxidizing agents.

Hazardous decomposition products :
No hazardous decomposition products known.

Disposal considerations

Waste treatment methods:
Product:
With respect to local regulations, e.g. dispose of to suitable waste incineration plant.

Uncleaned packaging:
Uncontaminated packaging may be recycled.
Dispose of as special waste in compliance with local and national regulations.