Registration Dossier

Classification & Labelling & PBT assessment

GHS

General Information

Name:
N,N-dimethylhydrazine self classification
Implementation:
EU
Type of classification:
self-classification
Remarks:

self classification based on available data in addition to harmonised classification according to Annex VI Tab. 3.1

Index No. 007-012-00-5

hygroscopic

Related composition

Related composition:
Composition 1
Composition 3

Classificationopen allclose all

Explosives
Reason for no classification:
conclusive but not sufficient for classification
Flammable gases and chemically unstable gases
Reason for no classification:
conclusive but not sufficient for classification
Aerosols
Reason for no classification:
conclusive but not sufficient for classification
Oxidising gases
Reason for no classification:
conclusive but not sufficient for classification
Gases under pressure
Reason for no classification:
conclusive but not sufficient for classification
Flammable liquids
Hazard category:
Flam. Liquid 2
Hazard statement:
H225: Highly flammable liquid and vapour.
Flammable solids
Reason for no classification:
conclusive but not sufficient for classification
Self-reactive substances and mixtures
Reason for no classification:
conclusive but not sufficient for classification
Pyrophoric liquids
Reason for no classification:
conclusive but not sufficient for classification
Pyrophoric solids
Reason for no classification:
conclusive but not sufficient for classification
Self-heating substances and mixtures
Reason for no classification:
conclusive but not sufficient for classification
Substances and mixtures which in contact with water emit flammable gases
Reason for no classification:
conclusive but not sufficient for classification
Oxidising liquids
Reason for no classification:
conclusive but not sufficient for classification
Oxidising solids
Reason for no classification:
conclusive but not sufficient for classification
Organic peroxides
Reason for no classification:
conclusive but not sufficient for classification
Corrosive to metals
Reason for no classification:
conclusive but not sufficient for classification
Desensitized explosives
Reason for no classification:
data lacking
Acute toxicity - oral
Hazard category:
Acute Tox. 3
Hazard statement:
H301: Toxic if swallowed.
Acute toxicity - dermal
Hazard category:
Acute Tox. 3
Hazard statement:
H311: Toxic in contact with skin.
Acute toxicity - inhalation
Hazard category:
Acute Tox. 3
Hazard statement:
H331: Toxic if inhaled.
Skin corrosion / irritation
Hazard category:
Skin Corr. 1B
Hazard statement:
H314: Causes severe skin burns and eye damage.
Serious eye damage / eye irritation
Reason for no classification:
conclusive but not sufficient for classification
Respiratory sensitisation
Reason for no classification:
conclusive but not sufficient for classification
Skin sensitisation
Reason for no classification:
conclusive but not sufficient for classification
Aspiration hazard
Reason for no classification:
conclusive but not sufficient for classification
Reproductive toxicity
Reason for no classification:
data lacking
Effects on or via lactation
Reason for no classification:
data lacking
Germ cell mutagenicity
Hazard category:
Muta. 2
Hazard statement:
H341: Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
Carcinogenicity
Hazard category:
Carc. 1B
Hazard statement:
H350: May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
1. Specific target organ toxicity - single
Hazard category:
STOT Single Exp. 3
Hazard statement:
H335: May cause respiratory irritation.
Affected organs:
lung
Route of exposure:
Inhalation
1. Specific target organ toxicity - repeated
Reason for no classification:
data lacking
Hazardous to the aquatic environment (acute / short-term)
Reason for no classification:
data lacking
Hazardous to the aquatic environment (long-term)
Hazard category:
Aquatic Chronic 2
Hazard statement:
H411: Toxic to aquatic life with long lasting effects.
Hazardous to the ozone layer
Reason for no classification:
data lacking

Labelling

Signal word:
Danger

Hazard pictogram

GHS02: flame
GHS05: corrosion
GHS06: skull and crossbones
GHS08: health hazard
GHS09: environment

Hazard statements

H225: Highly flammable liquid and vapour.
H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H331: Toxic if inhaled.
H314: Causes severe skin burns and eye damage.
H341: Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H350: May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H335: May cause respiratory irritation.
H411: Toxic to aquatic life with long lasting effects.

Precautionary statements

P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P240: Ground and bond container and receiving equipment.
P241: Use explosion-proof [electrical/ventilating/lighting/...] equipment.
P242: Use non-sparking tools.
P243: Take actions to pevent static discharges.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P270: Do no eat, drink or smoke when using this product.
P264: Wash ... thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P281: Use personal protective equipment as required.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/…
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352: IF ON SKIN: Wash with plenty of water/…
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313: IF exposed or concerned: Get medical advice/attention.
P330: Rinse mouth.
P370+P380+P375: In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P391: Collect spillage.
P403+P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.

Notes