Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Phototransformation in air

Currently viewing:

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
phototransformation in air
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Acceptable, well documented publication which meets basic scientific principles
Principles of method if other than guideline:
Review data with no special reference to the methods used in the experiments
GLP compliance:
no
Estimation method (if used):
PHOTOCHEMICAL REACTION WITH OH RADICALS
- Concentration of OH radicals: 500000 molecule/cm³
- Temperature for which rate constant was calculated: 298 (±20) Deg K
Light source:
not specified
Key result
% Degr.:
50
Sampling time:
3.7 d
Transformation products:
not specified

Rate constant cm3 • molecule-1• s-1: 8.72 x 10 -12

The half-life of n-octane, normalized to a 12-hour day, is 3.68 days, based on 12-hour light / 12-hour dark periods and an concentration of 5E5. The half-life is normalized to a 12-hour day because atmospheric oxidation reactions only take place in the presence of sunlight.

Validity criteria fulfilled:
not applicable
Conclusions:
The half-life of n-octane, normalized to a 12-hour day, is 3.7 days, based on 12-hour light / 12-hour dark periods and an OH- concentration of 5E5. The half-life is normalized to a 12-hour day because atmospheric oxidation reactions only take place in the presence of sunlight.
Executive summary:

The half-life of n-octane, normalized to a 12-hour day, is 3.7 days, based on 12-hour light / 12-hour dark periods and anconcentration of 5E5. The half-life is normalized to a 12-hour day because atmospheric oxidation reactions only take place in the presence of sunlight.

Description of key information

There is data available for this substance, which is presented in the dossier.

The half-life of n-octane, normalized to a 12-hour day, is 3.7 days, based on 12-hour light / 12-hour dark periods and anconcentration of 5E5. The half-life is normalized to a 12-hour day because atmospheric oxidation reactions only take place in the presence of sunlight.

Key value for chemical safety assessment

Additional information