Registration Dossier

Administrative data

First-aid measures

Eye contact
Flush eyes thoroughly with a large amount of water and consult a physician.

Skin contact
Wash off immediately with soap and water. If skin irritation occurs consult a
physician.

Inhalation
Move subject to fresh air and keep him calm. In case of complaints get medical
treatment.

Ingestion
Do not induce vomiting. Contact a doctor immediately.

General advice
Remove soiled, soaked clothing immediately. Medical treatment is necessary if
symptoms occur which are obviously caused by skin or eye contact with the
product or by inhalation of its vapours.

Fire-fighting measures

Suitable extinguishing media
dry chemical, carbon dioxide, alcohol-resistant foam

Extinguishing media which must not be used for safety reasons
water

Special protective equipment for firefighters
Wear self-contained breathing apparatus.

Accidental release measures

Personal precautions
Take care for adequate ventilation. Use personal protective clothing. Use breathing
apparatus if exposed to vapours/dust/mist/aerosol.

Environmental precautions
Prevent product from getting into drains/surface water/groundwater.

Methods for cleaning up
Larger quantities:
Take up mechanically (by pumping). Smaller quantities and/or
residues: Contain with absorbent material (e.g. sand, diatomaceous earth, acid
absorbent, universal absorbent or sawdust). Dispose of in accordance with
regulations.

Handling and storage

Safe handling advice
Keep container tightly closed. Provide good room ventilation even at ground level
(vapours are heavier than air).

Advice on protection against fire and explosion
In the event of fire, cool the endangered containers with water. When heated above
the flash point and/or during spraying (atomizing), ignitible mixtures may form in air.

Requirements for storage areas and containers
Protect from light. Fill the container by approximately 90 % only as oxygen (air) is
required for stabilisation. With large storage containers make sure the oxygen (air)
supply is sufficient to ensure stability. Keep only in the original container at a
temperature not exceeding 30 °C. Can polymerize with intense heat release.

Transport information

Land transport (ADR/RID)

Shippingopen allclose all
Remarks:
Not a dangerous good within the meaning of transportation regulations.

Inland waterway transport (ADN(R))

Shippingopen allclose all
Remarks
Not a dangerous good within the meaning of transportation regulations.

Marine transport (IMDG)

Remarks
Not a dangerous good within the meaning of transportation regulations.

Air transport ICAO/IATA

Remarks
Not a dangerous good within the meaning of transportation regulations.
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls
For monitoring procedures refer to for instance "Empfohlene Analysenverfahren für
Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and
"NIOSH Manual of Analytical Methods", National Institute for Occupational Safety
and Health

Protective measures
Do not inhale vapours. Avoid contact with eyes and skin.

Hygiene measures
Store work clothing separately. Remove soiled or soaked clothing immediately.
Follow the usual good standards of occupational hygiene. Clean skin thoroughly
after work; apply skin cream.

Respiratory protection
Breathing apparatus in case of high concentrations, short term: filter appliance,
filter A

Hand protection
butyl rubber gloves (0.7 mm), Break through time approx. 60 min (EN 374)
In practice, due to variable exposure conditions, this information can only be an aid
to orientation for the selection of a suitable chemical protection glove. In particular,
this information does not substitute suitability tests by the end user.

General information
Gloves should be replaced regularly, especially after extended contact with the
product. For each work-place a suitable glove type has to be selected.

Eye protection
tightly fitting goggles

Skin and body protection
On handling of larger quantities: face mask, chemical-resistant boots and apron

Stability and reactivity

Conditions to avoid
The product is normally supplied in a stabilized form. If the permissible storage
period and/or storage temperature is exceeded, the product may polymerize with
heat evolution.

Materials to avoid
Reactions with strong oxidizing agents.

Hazardous decomposition products
None when used as directed.

Thermal decomposition
No decomposition when used as directed.

Hazardous reactions
Polymerization with heat evolution may occur in the presence of radical forming
substances (e.g. peroxides), reducing substances, and/or heavy metal ions.

Disposal considerations

Product
Waste is hazardous. It must be disposed of in accordance with the regulations after
consultation of the competent local authorities and the disposal company in a
suitable and licensed facility.

Uncleaned packaging
Uncontaminated packaging may be taken for recycling. Contaminated packaging
should be emptied optimally and after appropriate professional cleansing may be
taken for reuse. Packaging that cannot be cleaned should be disposed of
professionally.

Code of waste
EWC 07 02 08
waste from the manufacture, formulation, supply and use (MFSU) of plastics,
synthetic rubber and man-made fibres - other still bottoms and reaction residues
Always check the given waste codes according to the actual conditions of
manufacturing, formulation or use in your facilities.