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Physical & Chemical properties

Auto flammability

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Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From 03 November 2016 to 10 November 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
2008
Deviations:
no
Qualifier:
according to guideline
Guideline:
IEC 60079-4 (Electrical apparatus for explosive gas atmospheres. Part 4: Method of test for ignition temperature)
Version / remarks:
1987
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
432 °C
Atm. press.:
100 kPa

Table: Results of the auto-ignition temperature measurements

 

Temperature (ºC)

Clean Flask (Yes/No)

Volume (µL)

Ignition Delay (s)

Observations

200

Yes

70

>300

No ignition, grey fumes emitted

250

Yes

70

>300

No ignition, grey fumes emitted

300

Yes

70

>300

No ignition, grey fumes emitted

350

No

70

>300

No ignition, grey fumes emitted

400

No

70

>300

No ignition, grey fumes emitted

450

No

70

8

Orange flame, grey fumes emitted

440

Yes

70

14

Orange flame, grey fumes emitted

430

Yes

70

>300

No ignition, grey fumes emitted

432

Yes

70

>300

No ignition, grey fumes emitted

434

No

70

>300

No ignition, grey fumes emitted

436

No

70

15

Orange flame, grey fumes emitted

434

Yes

70

19

Orange flame, grey fumes emitted

432

Yes

70

22

Orange flame, grey fumes emitted

430

Yes

70

>300

No ignition, grey fumes emitted

430

Yes

200

>300

No ignition, grey fumes emitted

430

Yes

400

>300

No ignition, grey fumes emitted

430

Yes

600

>300

No ignition, grey fumes emitted

430

Yes

800

>300

No ignition, grey fumes emitted

430

Yes

1000

>300

No ignition, grey fumes emitted

Conclusions:
The auto-ignition temperature at 100 kPa was determined to be 432°C.
Executive summary:

The auto-ignition temperature of the substance at 100 kPa was determined to be 432°C in a GLP study according to EC A.15 and IEC 79-4.

Description of key information

The auto-ignition temperature of the substance at 100 kPa was determined to be 432°C in a GLP study according to EC A.15 and IEC 79-4.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
432 °C

Additional information