Alkanes, C8-9-iso-

Guidance on Safe Use

First-aid measures

IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR EMERGENCY MEDICAL CARE.

Inhalation : Remove to fresh air.

- Symptoms : Headaches. Irritation of eyes (watering, conjunctivitis). Nasal irritation.

Dizziness. Nausea. Weariness.

Drowsiness. Vomiting. Irritability.

At high concentrations:

Drowsiness. Impairment of psychomotor functions (in particular dexterity, memory).

Ingestion : Do not induce vomiting to avoid the risk of aspiration into the respiratory tract.

Get medical attention immediately!

- Symptoms : Nausea, vomiting, abdominal pains, diarrhoea.

In the event of extensive ingestion :

Ulceration. Depression of the central nervous system.

In the event of ingestion with bronchial inhalation :

Pneumonopathy with respiratory distress.

Skin contact : Rinse with water.

Remove contaminated clothing.

- Symptoms :

Skin irritation. Erythema, oedema, pruritis

Eye contact : Rinse the eye with water immediately.

In case of splashing in the eyes:

Eye irritation (lachrymation, conjunctivitis).

Fire-fighting measures

Flash point:

see heading  - "Physical and chemical properties"

Extinguishing media : - suitable:

Foam, CO2, powder

- not recommended:

Water jet.

Specific fire-fighting methods : Cool down any tanks and surfaces exposed to fire by spraying abundantly with water.

Specific hazards : FLAMMABLE. Vapours are heavier than air and may spread on the ground to sources of

ignition. Vapours can build explosive mixtures with air.

Hazardous combustion products : Incomplete combustion and thermolysis may produce potentially toxic gases such as

carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These are

highly dangerous if inhaled.

Protective measures for firefighters : Insulated breathing apparatus must be worn in confined premises with heavy

concentrations of fumes and gases.

Use non-sparking handtools.

Other : All combustion residues and contaminated water from fire-fighting should be disposed of

according to local regulations.

Accidental release measures

Personal protection : Ensure good ventilation. Protective clothing, gloves, and goggles should be worn, as

applicable.

After spillage / leakage : Stop the leak by turning off the valve. Contain the spilled product. Do not allow the

product to enter sewers or rivers or contaminate the soil.

Contact the competent authorities if the situation cannot be brought under control rapidly

and efficiently.

Spill cleanup methods : - Recovery:

Use flame-proof and explosion-proof material. Contain and collect the spilled product

with sand or any other inert absorbent material. Preserve the waste in closed and sealed

recipients.

- Elimination:

Hand over contaminated materials to an approved collector - see also section 13.

Flush with plenty of water to clean spillage area.

Prevention of secondary risks : Remove all sources of ignition.

Handling and storage

HANDLING :

Prevention of user exposure : Ventilate extensively if the formation of vapours, fumes, mists or aerosol is a risk.

Prevention of fire and explosion : Handle away from any source of ignition (open flame and sparks) and heat (hot manifolds

or casings). Do not smoke.

Use explosion-proof material. Prevent any build-up of static electricity.

Do not use compressed oxygen or air when transferring or pouring the products.

Arrange machinery and equipment so as to prevent the sheet of burning product from

spreading (retention pits and basins, syphons in the water drainage system).

OPERATE ONLY ON COLD AND DEGASSED RESERVOIRS IN VENTILATED

PREMISES (TO AVOID RISK OF EXPLOSION).

Precautions : Avoid extended and repeated contact with the skin as this may cause skin conditions,

which may also be aggravated by minor injuries or by contact with soiled clothing.

Avoid breathing in vapours, fumes or mists.

Do not spray at high pressure (> 3 bar).

STORAGE :

Technical measures : Use anti-explosive materials conforming with the applicable regulations.

Prevent any build-up of static electricity.

Storage precautions : - Suitable:

Store away from all sources of ignition and heat.

Containers and equipments must be earthed in order to prevent sparks due to static

electricity.

Use only hydrocarbon resistant containers, joints, pipe-lines...

Keep in closed and accurately labelled containers when not in use.

Incompatible products : Dangerous reaction with strong acids and oxidizing agents.

Packaging materials : Steel, stainless steel

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN Number : 3295

Shipping

Labels:

3

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3295

Shipping

Labels:

3

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3295

Shipping

Labels:

3

Special provisions / remarks

Remarks:

Safety card : F-E, S-D

Air transport (UN RTDG/ICAO/IATA)

UN number:

3295

Shipping

Labels:

3

Special provisions / remarks

Remarks:

Special provisions : - ADR / RID / ADNR :
640D
649

SpecialProvisions

Exposure controls / personal protection

The personal protective equipment (PPE) recommendations apply to the product ITSELF. In case of mixtures or formulations, it is

suggested that you contact the relevant PPE suppliers.

Technical measures : Use this product in a well-ventilated atmosphere with explosion-proof equipment.

Occupational exposure limit : TOTAL FLUIDES recommends an occupational exposure limit (OEL) value for

hydrocarbon solvents of 1200 mg/m3 based on the CEFIC-HSPA (Brussels) guideline

values determined using the RCP (Reciprocal Calculation Procedure).

FRANCE C6 - C12 hydrocarbons vapours : VLE = 1500 mg/m3; VME = 1000 mg/m3

Respiratory protection : In case of risk of exposure exceeding the mean exposure value, an appropriate breathing

apparatus must be worn by each individual.

When using a mask or half-mask : Organic vapour cartridge, type A (if vapour inhalation

is a risk)

In case of vapours or sprays formation: Combined gas cartridge (organic gases and dust,

filter A/P2).

Be aware that filter protection time is limited.

Hand protection : Liquid proof aliphatic solvent resisting gloves :

- In case of splashes or limited contact :

Recommended materials:

Polychloroprene. Thickness > 0.7 mm - Permeation time according to EN 374-3 : > 60

minutes

Nitrile. Thickness > 0.3 mm Permeation time according to EN 374-3 : > 60 minutes

- In case of prolonged or repeated contact :

Nitrile. Thickness > 0.45 mm - Permeation time according to EN 374-3 : > 480 minutes

Fluoro polymer and PVA - any thickness. Permeation time according to EN 374-3 : > 480

minutes

For more precise details about the choice of appropriate protective glove, please contact

the manufacturer.

Eye protection : Goggles, in case of risk of splashing.

Skin and body (other than the hands) protection :

Appropriate protective clothing.

Hygienic work practices : Do not eat, drink or smoke whilst handling the product.

Avoid prolonged and repeated contact with the skin.

Do not dry hands with rags that have been contaminated with product.

Stability and reactivity

Stability : The product is stable at normal storage, handling and use temperatures.

Conditions to avoid : Heat (temperatures above flash point), sparks, ignition points, flames, static electricity

Materials to avoid : Strong acids and oxidising agents

Hazardous decomp. products : Incomplete combustion and thermolysis produces potentially toxic gases such as carbon

monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot.

Disposal considerations

Waste disposal : Prevent from entering sewers or the immediate environment.

- Relevant disposal method:

The only method authorized is collection by an authorized waste contractor and

regeneration or incineration in an approved installation.

Disposal of contaminated packaging : Hand over to an authorised waste contractor.

Empty packagings may contain flammable or explosive vapours.