Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Phototransformation in air

Currently viewing:

Administrative data

Endpoint:
phototransformation in air
Remarks:
Tropospheric removal
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
accepted calculation method

Data source

Reference
Reference Type:
publication
Title:
A global three-dimensional study of the fate of HCFCs and HFC-134a in the troposphere
Author:
Kanakidou M, Dentener FJ, Crutzen PJ
Year:
1995
Bibliographic source:
Journal of Geophysical research. Vol.100:18781-18801

Materials and methods

GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
Carbonyl difluoride
EC Number:
206-534-2
EC Name:
Carbonyl difluoride
Cas Number:
353-50-4
Molecular formula:
CF2O
IUPAC Name:
carbonyl difluoride
Test material form:
gas

Results and discussion

Dissipation half-life of parent compound
DT50:
3.9 d
Remarks on result:
other: estimation of hydrolysis in the clouds using Henry's law constant = 20 M.atm-1 and unimolecular hydrolysis rate k(H)= 8 sec-1 from George et al., 1993.
Remarks:
'Heterogeneous removal process)

Applicant's summary and conclusion

Conclusions:
The atmospheric lifetime of COF2 in cloud loss is reported to be 3.9 days. It is not expected to build up in the atmosphere.