2-fluoroaniline

Guidance on Safe Use

First-aid measures

4.1 Description of first aid measures

General advice In the case of accident or if you feel unwell, seek medical advice

immediately (show the label where possible).

Inhalation Move the victim to fresh air and keep at rest. In case of respiratory

arrest induce breathing with a respiratory device. Seek medical advice.

Skin contact Take off contaminated clothing and shoes immediately. Wash off

immediately with soap and plenty of water. Start medical treatment

immediately.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at

least 15 minutes. Eye treatment by an ophthalmologist.

Ingestion Do NOT induce vomiting. Never give anything by mouth to an

unconscious person. Rinse mouth. Call a physician or poison control

center immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms Breathing difficulties, Headache, Nausea

4.3 Indication of any immediate medical attention and special treatment needed

Treatment Treat symptomatically.

Fire-fighting measures

5.1 Extinguishing media

Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon

dioxide.

Unsuitable High volume water jet

5.2 Special hazards arising

from the substance or

mixture

Dangerous gases are evolved in the event of a fire., In the event of fire

the following may be released:, Carbon monoxide (CO), Carbon

dioxide (CO2), Nitrogen oxides (NOx), Hydrogen fluoride

5.3 Advice for firefighters

Special protective

equipment for firefighters

In the event of fire, wear self-contained breathing apparatus.

Further information Cool closed containers exposed to fire with water spray.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Precautions Use personal protective equipment. Ensure adequate ventilation.

Remove all sources of ignition. Evacuate and isolate spill area.

6.2 Environmental

precautions

Retain and dispose of contaminated wash water. Do not allow to get

into surface water, drains and ground water.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up Sweep up or vacuum up spillage and collect in suitable container for

disposal.

6.4 Reference to other

sections

Information regarding waste disposal, see section 13.

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with  REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4).  Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.  

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate. "

7.1 Precautions for safe handling

Advice on safe handling Avoid contact with skin, eyes and clothing.

Advice on protection

against fire and explosion

Keep away from heat and sources of ignition. Take measures to prevent

the build up of electrostatic charge.

Hygiene measures Avoid contact with skin, eyes and clothing. When using, do not eat, drink

or smoke.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage

areas and containers

Keep containers tightly closed in a cool, well-ventilated place.

Advice on common storage Keep away from food, drink and animal feedingstuffs.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

2941

Shipping information

Proper shipping name and description:

FLUOROANILINES

Chemical name:

2-Fluoroaniline

Language:

English

Labels:

Packaging 6.1
Haz ID 60
EAC 2X

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

2941

Shipping information

Proper shipping name and description:

FLUOROANILINES

Chemical name:

2-Fluoroaniline

Language:

English

Labels:

Packaging 6.1
Haz ID 60

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

2941

Shipping information

Proper shipping name and description:

FLUOROANILINES

Chemical name:

2-Fluoroaniline

Labels:

Packaging 6.1
Bulk 6.1

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

2941

Shipping information

Proper shipping name and description:

FLUOROANILINES

Chemical name:

2-Fluoroaniline

Labels:

Packaging 6.1

Remarks

SpecialProvisions

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with  REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4).  Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.  

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate. "

 

8.1 Control parameters

No known occupational limit values.

8.2 Exposure controls

Respiratory protection Respiratory protection in case of insufficient exhaust ventilation or

prolonged exposure:

Multi-range filter ABEK/P2

When respirators are required, select NIOSH approved equipment

based on actual or potential airborne concentrations and in

accordance with the appropriate regulatory standards and/or industry recommendations.

Hand protection Protective gloves

Please observe the instructions regarding permeability and

breakthrough time which are provided by the supplier of the gloves.

Also take into consideration the specific local conditions under which

the product is used, such as the danger of cuts, abrasion, and the

contact time.

Wear suitable gloves tested to EN374.

Eye protection Tightly fitting safety goggles

Face-shield

Skin and body protection complete suit protecting against chemicals

Use suitable protective clothing, gloves and footwear, selected with

regard to use conditions and exposure potential.

General protective measures Avoid contact with skin and eyes.

Wash skin after work

Stability and reactivity

10.1 Reactivity

Thermal decomposition No data available

10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of

hazardous reactions

No hazardous reactions known.

10.4 Conditions to avoid Heat, flames and sparks.

10.5 Incompatible materials Acid chlorides, Acid anhydrides, Acids, Strong oxidizing agents

10.6 Hazardous

decomposition products

Carbon monoxide

Carbon dioxide (CO2)

Hydrogen fluoride

Nitrogen oxides (NOx)

Disposal considerations

During the whole life cycle of the substance all necessary measures in accordance to art. 18(4) of (EC) 1907/2006 are undertaken. The substance is handled under strictly controlled conditions.

 

Dispose in accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.