Notified classification and labelling according to CLP criteria
General Section
EC / List no.
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Name |
CAS Number
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Additional Notified Information
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941-496-7 | 1,1’-Methylenebis(4-isocyanatobenzene) and its reaction products with [(methylethylene)bis(oxy)]dipropanol, butane-1,3-diol and propylene glycol |
State/Form
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Classification | Labelling | Specific Concentration limits, M-Factors | Notes |
Classification affected by Impurities / Additives
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Hazard Class and Category Code(s) | Hazard Statement Code(s) | Hazard Statement Code(s) | Supplementary Hazard Statement Code(s) | |||
Skin Irrit. 2 | H315 | H315 | EUH204 |
Eye Irrit. 2; : C ≥ 5 % Resp. Sens. 1; : C ≥ .1 % STOT SE 3; : C ≥ 5 % Skin Irrit. 2; : C ≥ 5 % |
Note 2
Note C |
|
Skin Sens. 1 | H317 | H317 | ||||
Eye Irrit. 2 | H319 | H319 | ||||
Acute Tox. 4 | H332 | H332 | ||||
Resp. Sens. 1 | H334 | H334 | ||||
STOT SE 3 | H335 (other:respirato...) (inhalation) | H335 | ||||
Carc. 2 | H351 | H351 | ||||
STOT RE 2 | H373 (other:respirato...) (inhalation) | H373 (respiratory sys...) |
Signal Words | Pictograms | ||||||
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Danger |
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Detailed Information on classification and labelling
Classification
Physical and Chemical hazards | |||
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Hazard Category | Hazard Statement |
Reason for no Classification
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Explosives | data conclusive but not sufficient for classification | ||
Flammable Gases and Chemically Unstable Gases | data conclusive but not sufficient for classification | ||
Flammable Aerosols | data conclusive but not sufficient for classification | ||
Oxidising Gases | data conclusive but not sufficient for classification | ||
Gases Under Pressure | data conclusive but not sufficient for classification | ||
Flammable Liquids | data conclusive but not sufficient for classification | ||
Flammable Solids | data conclusive but not sufficient for classification | ||
Self-reactive Substances and Mixtures | data conclusive but not sufficient for classification | ||
Pyrophoric Liquids | data conclusive but not sufficient for classification | ||
Pyrophoric Solids | data conclusive but not sufficient for classification | ||
Self-heating Substances and Mixtures | data conclusive but not sufficient for classification | ||
Substances and Mixtures which in contact with water emit flammable gases | data conclusive but not sufficient for classification | ||
Oxidising Liquids | data conclusive but not sufficient for classification | ||
Oxidising Solids | data conclusive but not sufficient for classification | ||
Organic Peroxides | data conclusive but not sufficient for classification | ||
Substances and Mixtures corrosive to Metals | data conclusive but not sufficient for classification | ||
Desensitized Explosives | data lacking | ||
Human Health hazards | |||
Hazard Category | Hazard Statement |
Reason for no Classification
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Acute Toxicity - Oral | data conclusive but not sufficient for classification | ||
Acute Toxicity - Dermal | data conclusive but not sufficient for classification | ||
Acute Toxicity - Inhalation | Acute Tox. 4 | H332 | |
Skin Corrosion / Irritation | Skin Irrit. 2 | H315 | |
Serious Eye Damage / Eye Irritation | Eye Irrit. 2 | H319 | |
Respiratory Sensitisation | Resp. Sens. 1 | H334 | |
Skin Sensitisation | Skin Sens. 1 | H317 | |
Aspiration Hazard | data inconclusive | ||
Germ Cell Mutagenicity | Hazard Category | Hazard Statement |
Reason for no Classification
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Germ Cell Mutagenicity | data conclusive but not sufficient for classification | ||
Carcinogenicity | Hazard Category | Hazard Statement |
Reason for no Classification
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Carcinogenicity | Carc. 2 | H351 | |
Reproductive Toxicity | Hazard Category | Hazard Statement |
Reason for no Classification
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Reproductive Toxicity | data conclusive but not sufficient for classification | ||
Effects on or via Lactation | data conclusive but not sufficient for classification | ||
Specific target organ toxicity - Single | Hazard Category | Hazard Statement |
Reason for no Classification
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Specific target organ toxicity - Single | STOT SE 3 | H335 | |
Affected Organs | other:respiratory system | ||
Route of exposure | inhalation | ||
Specific target organ toxicity - Repeated | Hazard Category | Hazard Statement |
Reason for no Classification
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Specific target organ toxicity - Repeated | STOT RE 2 | H373 | |
Affected Organs | other:respiratory system | ||
Route of exposure | inhalation | ||
Environmental Hazards | |||
Hazardous to the aquatic environment | Hazard Category | Hazard Statement |
Reason for no Classification
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Hazardous to the aquatic environment - acute | data conclusive but not sufficient for classification | ||
Hazardous to the aquatic environment - chronic | data conclusive but not sufficient for classification | ||
Hazardous to the atmospheric environment | Hazard Category | Hazard Statement |
Reason for no Classification
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Hazardous to the ozone layer | data lacking |
Additional Hazard Classes | Additional Hazard Statements |
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No available Data |
Labelling
Hazard Statement Code(s) | Phrase | Additional Text |
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H315 | Causes skin irritation. | |
H319 | Causes serious eye irritation. | |
H317 | May cause an allergic skin reaction. | |
H332 | Harmful if inhaled. | |
H335 | May cause respiratory irritation. | |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled. | |
H351 | Suspected of causing cancer |
|
H373 | May cause damage to organs |
respiratory system - inhalation |
Note Title | Note Text |
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Note 2 | The concentration of isocyanate stated is the percentage by weight of the free monomer calculated with reference to the total weight of the mixture. |
Note C | Some organic substances may be marketed either in a specific isomeric form or as a mixture of several isomers. , In this case the supplier must state on the label whether the substance is a specific isomer or a mixture of isomers. |